S. Ajao Adeyemi scite author profile

The reaction Ru(bipy)2(NO)X2 + + Ns~+ S Ru(bipy)2SX+ + N2 + N20 (S = solvent; X = Cl, N02) has been usedto prepare a series of solvent complexes. For X = N02, mixtures of nitro and nitrito isomers are obtained as products. Displacement of coordinated acetone in Ru(bipy)2(OC(CH3)2)X + has provided a general route to the cis complexes Ru-(bipy)2YX+'°(Y = neutral or anionic ligand). During the substitution reactions of Ru(bipy)2(0C(CH3)2)N02+, nitritonitro interconversion also occurs.

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Novel cis-directed, four-electron dioxo oxidant

Dovletoglou¹,

Adeyemi²,

Lynn³

et al. 1990

J. Am. Chem. Soc.

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S. Ajao Adeyemi

Chemically significant interactions between ruthenium ions in oxo-bridged complexes of ruthenium(III)

Synthesis and properties of the chloro-bridged dimer [(bpy)2RuCl]22+ and its transient 3+ mixed-valence ion

Redox and spectral properties of the four-electron oxidant trans-aquadioxo(terpyridine)ruthenium(2+) diperchlorate

Synthetic aspects of the reaction between azide ion and Ru(bipy)2(NO)X2+ (X = Cl, NO2). Substitution-induced nitro-nitrito isomerism

Novel cis-directed, four-electron dioxo oxidant

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