The application of Rietveld texture analysis (RTA) to time-of-flight (TOF) neutron diffraction data allows complex materials with many diffraction peaks to be investigated, for example, rocks composed of different minerals. At the recently upgraded SKAT texture diffractometer at the JINR in Dubna (Russia), which provides three alternative multidetector systems, resolution and accessible range of lattice d spacings can be adapted to sample requirements. In order to infer the optimum experimental setup and the reliability of texture estimates from complicated TOF patterns, the influence of counting statistics and various spectral resolutions on texture deconvolution was investigated. Comparing the results obtained at different resolutions and from different sections of the d patterns indicates that the textures of a four-phase sample can be determined, but using a section at small d spacings with a larger number of peak overlaps leads to smoother textures. A complex seven-phase sample shows orientation differences in addition to the smoothing effect. Weak textures and textures of the minor rock constituents are inaccurate owing to multiple peak overlaps. Consequently, good resolution is essential for RTA on such samples. Grid thinning tests confirmed that no more than 150 diffraction spectra are needed to characterize the texture of a monomineralic sample, and approximately 350 spectra are sufficient for a four-phase sample. The irregular grid point arrangement caused by the SKAT geometry has no negative consequences. research papers J. Appl. Cryst. (2014). 47, 1520-1534 Ruth Keppler et al. Potential of full pattern fit methods for texture analysis 1521 Figure 1Energy distribution of thermal neutrons at the IBR-2M reactor applying a water moderator at ambient conditions; the time of flight and wavelength range of the SKAT related to the accessible d ranges for various diffraction angles 2. research papers J. Appl. Cryst. (2014). 47, 1520-1534 Ruth Keppler et al. Potential of full pattern fit methods for texture analysis 1531

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Many blueschists and eclogites are inferred to have formed from oceanic basalts in subducted slabs. Knowledge of their elastic behavior is essential for reconstructing the internal structure of subduction zones. The Cycladic blueschist unit, exposed on Syros Island (Greece), contains rocks belonging to an exhumed Tertiary subduction complex. They were possibly part of a subduction channel, a shear zone above the subducting slab in which exhumation is possible during subduction. Intense plastic deformation, forming crystallographic preferred orientations (CPO), accompanied blueschist and eclogite metamorphism. CPO of the constituent minerals in the collected samples was determined by time‐of‐flight neutron diffraction. Two samples are foliated fine‐grained blueschists with strong CPO, rich in glaucophane, zoisite, and phengite. Two coarser‐grained eclogite samples rich in omphacite and clinozoisite, or glaucophane, have weaker CPO. Vp and Vs anisotropies were computed from the orientation distribution function and single‐crystal elastic constants. All samples show velocity maxima parallel to the mineral lineation, and minima normal to the foliation, providing important constraints on orientations of seismic anisotropy in subduction channels. Vp anisotropies are up to 3 times higher (6.5–12%) in the blueschists than in the eclogites (3–4%), pointing to a potentially important lithological control of elastic anisotropy in subducted oceanic crust.

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Subduction zone processes and the resulting geometries at depth are widely studied by large‐scale geophysical imaging techniques. The subsequent interpretations are dependent on information from surface exposures of fossil subduction and collision zones, which help to discern probable lithologies and their structural relationships at depth. For this purpose, we collected samples from Holsnøy in the Bergen Arcs of western Norway, which constitutes a well‐preserved slice of continental crust, deeply buried and partially eclogitized during Caledonian collision. We derived seismic properties of both the lower crustal granulite‐facies protolith and the eclogite‐facies shear zones by performing laboratory measurements on cube‐shaped samples. P and S wave velocities were measured in three perpendicular directions, along the principal fabric directions of the rock. Resulting velocities agree with seismic velocities calculated using thermodynamic modeling and confirm that eclogitization causes a significant increase of the seismic velocity. Further, eclogitization results in decreased VP/VS ratios and, when associated with deformation, an increase of the seismic anisotropy due to the crystallographic preferred orientation of omphacite that were obtained from neutron diffraction measurements. The structural framework of this exposed complex combined with the characteristic variations of seismic properties from the lower crustal protolith to the high‐pressure assemblage provides the possibility to detect comparable structures at depth in currently active settings using seismological methods such as the receiver function method.

Abstract. Subduction and exhumation are key processes in the formation of orogenic systems across the world, for example, in the European Alps. For geophysical investigations of these orogens, it is essential to understand the petrophysical properties of the rocks involved. These are the result of a complex interaction of mineral composition and rock fabric including mineral textures (i.e., crystallographic preferred orientations). In this study we present texture-derived elastic anisotropy data for a representative set of different lithologies involved in the Alpine orogeny. Rock samples were collected in the Lago di Cignana area in Valtournenche, in the Italian northwestern Alps. At this locality a wide range of units of continental and oceanic origin with varying paleogeographic affiliations and tectono-metamorphic histories are accessible. Their mineral textures were determined by time-of-flight neutron diffraction. From these data the elastic properties of the samples were calculated. The data set includes representative lithologies from a subduction-exhumation setting. In subducted lithologies originating from the oceanic crust, the P-wave anisotropies (AVPs [%]) range from 1.4 % to 3.7 % with average P-wave velocities of 7.20–8.24 km/s and VP / VS ratios of 1.70–1.75. In the metasediments of the former accretionary prism the AVPs range from 3.7 % to 7.1 %, average P-wave velocities are 6.66–7.23 km/s and VP / VS ratios are 1.61–1.76. Continental crust which is incorporated in the collisional orogen shows AVP ranging from 1.4 % to 2.1 % with average P-wave velocities of 6.52–6.62 km/s and VP / VS ratios of 1.56–1.60. Our results suggest that mafic and felsic rocks in subduction zones at depth may be discriminated by a combination of seismic signatures: lower anisotropy and higher VP / VS ratio for mafic rocks, and higher anisotropy and lower VP / VS ratio for felsic rocks and metasediments.

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