Stable Pickering emulsions were prepared using only graphene oxide (GO) as a stabilizer, and the effects of the type of oil, the sonication time, the GO concentration, the oil/water ratio, and the pH value on the stability, type, and morphology of these emulsions were investigated. In addition, the effects of salt and the extent of GO reduction on emulsion formation and stability were studied and discussed. The average droplet size decreased with sonication time and with GO concentration, and the emulsions tended to achieve good stability at intermediate oil/water ratios and at low pH values. In all solvents, the emulsions were of the oil-in-water type, but interestingly, some water-in-oil-in-water (w/o/w) multiple emulsion droplets were also observed with low GO concentrations, low pH values, high oil/water ratios, high salt concentrations, or moderately reduced GO in the benzyl chloride-water system. A Pickering emulsion stabilized by Ag/GO was also prepared, and its catalytic performance for the reduction of 4-nitrophenol was investigated. This research paves the way for the fabrication of graphene-based functional materials with novel nanostructures and microstructures.
An environmentally friendly approach to reduce graphene oxide (GO) with L-lysine (L-Lys) was developed by using carboxymethyl starch (CMS) as a stabilizing agent and a stable suspension of reduced graphene oxide (RGO) was obtained. UV visible absorption spectroscopy was used to monitor the deoxygenating process and the factors that affect the GO reduction, such as the ratio of GO/L-Lys, the temperature and pH were optimized. The reduction of the GO was verified by Fourier transform infrared spectroscopy, Xray diffraction, thermo-gravimetric analysis, Raman spectroscopy and X-ray photoelectron spectroscopy.Ordered porous RGO/CMS foams were prepared by a unidirectional freeze-drying method (UFDM) and used as absorbents for copper ions. Since L-Lys and CMS are natural and edible chemicals, this approach provides a green method to produce stable RGO from GO on a large scale. The nontoxic biodegradable RGO/CMS foams show potential applications for metal ions removal from wastewater.
This paper proposes an approved Web-based multilayer distributed software architecture solution for remote monitoring and fault diagnosis. To tightly integrate legacy monitor systems, a component framework model based on COM has been proposed, which is very suitable for remote monitoring and fault diagnosis applications. This system has the potential for exchanging a data acquisition system by using wrapper service components. A mixed thick Web client architecture is proposed to implement real-time remote monitoring. A Web-based remote monitoring and fault diagnosis system is developed by using modeling technology, Web application technology, component technology and VME extension for instrumentation (VXI) bus technology, which publishes a fault diagnosis algorithm package, a basic monitoring package and an advanced analysis package on the Internet. This system provides authorized users with an effective and instant way to access new monitoring and diagnosis component packages in time. This paper gives researchers a paradigm to accomplish similar systems. The technique developed may be used for other fields, such as power engineering, manufacture and transportation system.
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