The
development of photocatalysts toward highly efficient H2 evolution reactions is a feasible strategy to achieve the
effective conversion of solar energy and meet the increasing demand
for new energy. To this end, we prepared two different CdS–MoS2 photocatalysts with unique morphologies ranging from hexagonal
prisms to tetragonal nanotubes by carefully tuning polyoxometalate
synthons. These two photocatalysts, namely, CdS–MoS2-1 and CdS–MoS2-2, both exhibited remarkable photocatalytic
efficiency in H2 generation, among which CdS–MoS2-2 showed superior performance. In fact, the best catalytic
hydrogen desorption rate of CdS–MoS2-2 is as high
as 1815.5 μmol g–1 h–1.
Such performance is superior to twice that of single CdS and almost
four times that of pure MoS2. This obvious enhancement
can be accredited to the highly open nanotube morphology and highly
dispersed heterometallic composition of CdS–MoS2-2, which represents an excellent example of the highest noble-metal-free
H2 evolution photocatalysts reported so far. Taken together,
these findings suggest that the development of highly dispersed heterometallic
catalysts is an auspicious route to realize highly efficient conversion
of solar energy and that CdS–MoS2-2 represents a
major advance in this field.
A new polyoxometelate (POM)-based metal-organic framework (POMOF) (HSiW12O40)[MnIII(L)3][MnII(L)3]·4H2O, (L = 3-pyraziny-1,2,4-triazole) was synthesized by hydrothermal reaction, and characterized by single crystal X-ray diffraction, infrared spectroscopy, powder X-ray diffraction and solid-state...
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