To improve our understanding of the role of electromagnetic ion cyclotron (EMIC) waves in radiation belt electron dynamics, we perform a comprehensive analysis of EMIC wave‐induced resonant scattering of outer zone relativistic (>0.5 MeV) electrons and resultant electron loss time scales with respect to EMIC wave band, L shell, and wave normal angle model. The results demonstrate that while H+‐band EMIC waves dominate the scattering losses of ~1–4 MeV outer zone relativistic electrons, it is He+‐band and O+‐band waves that prevail over the pitch angle diffusion of ultrarelativistic electrons at higher energies. Given the wave amplitude, EMIC waves at higher L shells tend to resonantly interact with a larger population of outer zone relativistic electrons and drive their pitch angle scattering more efficiently. Obliquity of EMIC waves can reduce the efficiency of wave‐induced relativistic electron pitch angle scattering. Compared to the frequently adopted parallel or quasi‐parallel model, use of the latitudinally varying wave normal angle model produces the largest decrease in H+‐band EMIC wave scattering rates at pitch angles < ~40° for electrons > ~5 MeV. At a representative nominal amplitude of 1 nT, EMIC wave scattering produces the equilibrium state (i.e., the lowest normal mode under which electrons at the same energy but different pitch angles decay exponentially on the same time scale) of outer belt relativistic electrons within several to tens of minutes and the following exponential decay extending to higher pitch angles on time scales from <1 min to ~1 h. The electron loss cone can be either empty as a result of the weak diffusion or heavily/fully filled due to approaching the strong diffusion limit, while the trapped electron population at high pitch angles close to 90° remains intact because of no resonant scattering. In this manner, EMIC wave scattering has the potential to deepen the anisotropic distribution of outer zone relativistic electrons by reshaping their pitch angle profiles to “top‐hat.” Overall, H+‐band and He+‐band EMIC waves are most efficient in producing the pitch angle scattering loss of relativistic electrons at ~1–2 MeV. In contrast, the presence of O+‐band EMIC waves, while at a smaller occurrence rate, can dominate the scattering loss of 5–10 MeV electrons in the entire region of the outer zone, which should be considered in future modeling of the outer zone relativistic electron dynamics.

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A highly efficient bifunctional oxygen catalyst is required for practical applications of fuel cells and metal-air batteries, as oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are their core electrode reactions. Here, the MO-Co@N-doped carbon (NC, M = Zn or Co) is developed as a highly active ORR/OER bifunctional catalyst via pyrolysis of a bimetal metal-organic framework containing Zn and Co, i.e., precursor (CoZn). The vital roles of inactive Zn in developing highly active bifunctional oxygen catalysts are unraveled. When the precursors include Zn, the surface contents of pyridinic N for ORR and the surface contents of Co-N x and Co 3+ /Co 2+ ratios for OER are enhanced, while the high specific surface areas, high porosity, and high electrochemical active surface areas are also achieved. Furthermore, the synergistic effects between Zn-based and Co-based species can promote the well growth of multiwalled carbon nanotubes (MWCNTs) at high pyrolysis temperatures (≥700 °C), which is favorable for charge transfer. The optimized CoZn-NC-700 shows the highly bifunctional ORR/OER activity and the excellent durability during the ORR/OER processes, even better than 20 wt% Pt/C (for ORR) and IrO 2 (for OER). CoZn-NC-700 also exhibits the prominent Znair battery performance and even outperforms the mixture of 20 wt% Pt/C and IrO 2 .

This is a companion study to Liang et al. (2014) which reported a “reversed” energy‐latitude dispersion pattern of ion precipitation in that the lower energy ion precipitation extends to lower latitudes than the higher‐energy ion precipitation. Electromagnetic ion cyclotron (EMIC) waves in the central plasma sheet (CPS) have been suggested to account for this reversed‐type ion precipitation. To further investigate the association, we perform a comprehensive study of pitch angle diffusion rates induced by EMIC wave and the resultant proton loss timescales at L = 8–12 around the midnight. Comparing the proton scattering rates in the Earth's dipole field and a more realistic quiet time geomagnetic field constructed from the Tsyganenko 2001 (T01) model, we find that use of a realistic, nondipolar magnetic field model not only decreases the minimum resonant energies of CPS protons but also considerably decreases the limit of strong diffusion and changes the proton pitch angle diffusion rates. Adoption of the T01 model increases EMIC wave diffusion rates at > ~ 60° equatorial pitch angles but decreases them at small equatorial pitch angles. Pitch angle scattering coefficients of 1–10 keV protons due to H+ band EMIC waves can exceed the strong diffusion rate for both geomagnetic field models. While He+ and O+ band EMIC waves can only scatter tens of keV protons efficiently to cause a fully filled loss cone at L > 10, in the T01 magnetic field they can also cause efficient scattering of ~ keV protons in the strong diffusion limit at L > 10. The resultant proton loss timescales by EMIC waves with a nominal amplitude of 0.2 nT vary from a few hours to several days, depending on the wave band and L shell. Overall, the results demonstrate that H+ band EMIC waves, once present, can act as a major contributor to the scattering loss of a few keV protons at lower L shells in the CPS, accounting for the reversed energy‐latitude dispersion pattern of proton precipitation at low energies (~ keV) on the nightside. The pitch angle coverage for H+ band EMIC wave resonant scattering strongly depends on proton energy, L shell, and field model. He+ and O+ band EMIC waves tend to cause efficient scattering loss of protons at higher energies, thereby importantly contributing to the isotropic distribution of higher energy (> ~ 10 keV) protons at higher L shells on the nightside where the geomagnetic field line is highly stretched. Our results also suggest that scattering by H+ band EMIC waves may significantly contribute to the formation of the reversed‐type CPS proton precipitation on the dawnside where both the wave activity and occurrence probability is statistically high.

Whistler mode wave properties inside the plasmasphere and plumes are systematically investigated using 5‐year data from Van Allen Probes. The occurrence and intensity of whistler mode waves in the plasmasphere and plumes exhibit dependences on magnetic local time, L, and AE. Based on the dependence of the wave normal angle and Poynting flux direction on L shell and normalized wave frequency to electron cyclotron frequency (fce), whistler mode waves are categorized into four types. Type I: ~0.5 fce with oblique wave normal angles mostly in plumes; Type II: 0.01–0.5 fce with small wave normal angles in the outer plasmasphere or inside plumes; Type III: <0.01 fce with oblique wave normal angles mostly within the plasmasphere or plumes; Type IV: 0.05–0.5 fce with oblique wave normal angles deep inside the plasmasphere. The Poynting fluxes of Type I and II waves are mostly directed away from the equator, suggesting local amplification, whereas the Poynting fluxes of Type III and IV are directed either away from or toward the equator, and may originate from other source regions. Whistler mode waves in plumes have relatively small wave normal angles with Poynting flux mostly directed away from the equator and are associated with high electron fluxes from ~30 keV to hundreds of keV, all of which support local amplification. Whistler mode wave amplitudes in plumes can be stronger than typical plasmaspheric hiss, particularly during active times. Our results provide critical insights into understanding whistler mode wave generation inside the plasmasphere and plumes.