High entropy alloy attracts great attention for its high thermal stability and corrosion resistance. A CoCrFeNiMn high-entropy alloy coating was deposited on grey cast iron through plasma transfer arc cladding. It formed fine acicular martensite near the grey cast iron, with columnar grains perpendicular to the interface between the grey cast iron substrate and the cladding layer as well as dendrite in the middle part of the coatings. Simple FCC solid solutions present in the coatings which were similar to the powder’s structure. The coating had a microhardness of 300 ± 21.5 HV0.2 when the cladding current was 80 A for the solid solution strengthening. The HEA coating had the highest corrosion potential of −0.253 V when the plasma current was 60 A, which was much higher than the grey cast iron’s corrosion potential of −0.708 V. Meanwhile, the coating had a much lower corrosion current density of 9.075 × 10−7 mA/cm2 than the grey cast iron’s 2.4825 × 10−6 mA/cm2, which reflected that the CoCrFeNiMn HEA coating had much better corrosion resistance and lower corrosion rate than the grey cast iron for single FCC solid solution phase and a relatively higher concentration of Cr in the grain boundaries than in the grains and this could lead to corrosion protection effects.
High-entropy alloys receive more attention for high strength, good ductility as well as good wear resistance. In this work, CoCrFeNiMn high-entropy alloy (HEA) coatings were deposited on compacted graphite iron through plasma transfer arc at different currents. The microstructure and wear properties of the CoCrFeNiMn HEA coatings were investigated. The coatings are composed of single phase with FCC structure. The CoCrFeNiMn HEA coating had the highest microhardness of 394 ± 21.6 HV0.2 and the lowest wear mass loss when the plasma current was 65 A. All of the HEA coatings had higher friction coefficients than that of the substrate. There were adhesive, abrasive and oxidation wear forms in the HEA coatings with the wear couple of N80 alloy. The HEA coating presented higher friction coefficient and better wear resistance than compacted graphite iron.
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