Mixed
surfactants have a prominent synergistic effect and show
advantages in many aspects. In this work, the effects of a mixture
of dodecyltrimethylammonium bromide (DTAB) and sodium dodecyl sulfate
(SDS) on the flotation of low-rank coal were studied from the wetting
rate, contact angle, surface tension, and zeta potential. Furthermore,
the adsorption configuration of the mixed surfactant on the surface
of oxygen-containing graphite was simulated at the molecular level
by molecular dynamics simulation. The experimental results show that
the combustible matter recovery of low-rank coal flotation is improved
using the mixed surfactant, and the contact angle test and wetting
rate test confirmed the synergistic effect of the mixed surfactant.
In the mixed surfactant system, the addition of SDS with an opposite
charge to DTAB can reduce the mutual repulsion between DTAB molecules
and enhance the degree of DTAB alignment in solution, which was analyzed
by surface tension and zeta potential tests. Meanwhile, the simulation
results reveal the adsorption behavior of anionic and cationic surfactants
on the surface of oxygen-containing graphite from the molecular level
and also verify the experimental results. This investigation provides
a good understanding of the interaction mechanism of mixed surfactants
in low-rank coal flotation.
Coal chars are usually produced under complex atmospheres in industrial production. However, most of the research about char characteristics and gasification reactivity uses the coal char samples prepared under an inert atmosphere. In this study, the influences of the pyrolysis atmosphere and temperature on coal char characteristics and gasification reactivity were investigated. A Shanxi bituminous coal was pyrolyzed in a bubbling fluidized bed to produce char samples. A mixture of hydrogen (H2), carbon dioxide (CO2), carbon monoxide (CO), and methane (CH4) was used as simulated pyrolysis gas (SPG). The coal was pyrolyzed in the SPG and N2 atmospheres, respectively. SEM, Raman spectroscopy, and FTIR spectroscopy were used to study the influences of the pyrolysis atmosphere and temperature on the coal char characteristics. The char–H2O and char–CO2 gasification reactivities were measured by using a modified thermogravimetric analysis (TGA) system. The experimental results indicate that the SPG atmosphere has no obvious influence on the coal char morphology, but it has significant influences on the carbon structures and surface chemical groups. The SPG char samples have lower gasification reactivity. The disproportionation reaction of CO, the decomposition reaction of CH4, and the loss of oxygen‐containing structures induced by H2 lead to a higher‐ordered degree of char, and the graphite generated from the disproportionation reaction and the decomposition reaction can decrease the specific surface area of the coal char. These two reasons result in the lower gasification reactivity of SPG char.
Abstract:Hydraulic fracturing is an important technique for increasing coal seam permeability and productivity of CBM (coalbed methane). As a common type of faulted structure in the coal seam, the fault has a direct impact on the direction and scope of hydrofracture propagation, weakening fracturing effects. To study the propagation laws of a hydrofracture meeting a fault in the coal seam, based on a two-dimensional model of a hydrofracture meeting a fault, the combined elastic mechanics and fracture mechanics, the propagation mode, critical internal water pressure, and influencing factors were analyzed. A numerical simulation on the propagation laws of hydrofracture meeting a fault was conducted by using the coupling system of flow and solid in the rock failure process analysis (RFPA2D-Flow). The results show that the horizontal crustal stress difference, the intersection angle between hydrofracture and fault plane, and the physical mechanics characteristics of coal-rock bed are the main factors influencing fracture propagation. With a decrease of horizontal crustal stress differences, intersection angle and an increase of roof elasticity modulus, it is easier for the footwall hydrofracture to enter the hanging wall along the bedding plane, forming an effective fracture. When the stress difference is large and the dip angle of fault plane surpasses 45 • , the hydrofracture is easy to propagate towards the coal roof and floor by going through the fault plane. At this time, the coal seams of the footwall and the hanging wall should be fractured respectively to ensure fracturing effects, and the support of the roof and floor should be strengthened. The field experiment, theoretical analysis and numerical simulation were consistent in their results, which will contribute to the optimization of hydraulic fracturing and the prediction of hydrofracture in the coal seams containing faults.
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