Fluctuation theorems make use of time reversal to make predictions about entropy production in many-body systems far from thermal equilibrium. Here we review the wide variety of distinct, but interconnected, relations that have been derived and investigated theoretically and experimentally. Significantly, we demonstrate, in the context of Markovian stochastic dynamics, how these different fluctuation theorems arise from a simple fundamental time-reversal symmetry of a certain class of observables. Appealing to the notion of Gibbs entropy allows for a microscopic definition of entropy production in terms of these observables. We work with the master equation approach, which leads to a mathematically straightforward proof and provides direct insight into the probabilistic meaning of the quantities involved. Finally, we point to some experiments that elucidate the practical significance of fluctuation relations.

Abstract.We discuss the long-time limit of the integrated current distribution for the onedimensional zero-range process with open boundaries. We observe that the current fluctuations become site-dependent above some critical current and argue that this is a precursor of the condensation transition which occurs in such models. Our considerations for the totally asymmetric zero-range process are complemented by a Bethe ansatz treatment for the equivalent exclusion process.

We consider the behaviour of current fluctuations in the one-dimensional partially asymmetric zero-range process with open boundaries. Significantly, we find that the distribution of large current fluctuations does not satisfy the Gallavotti-Cohen symmetry and that such a breakdown can generally occur in systems with unbounded state space. We also discuss the dependence of the asymptotic current distribution on the initial state of the system.

We consider the fluctuations of generalized currents in stochastic Markovian dynamics. The large deviations of current fluctuations are shown to obey a Gallavotti-Cohen (GC) type symmetry in systems with a finite state space. However, this symmetry is not guaranteed to hold in systems with an infinite state space. A simple example of such a case is the zero-range process (ZRP). Here we discuss in more detail the already reported (Harris et al 2006 Europhys. Lett. 75 227) breakdown of the GC symmetry in the context of the ZRP with open boundaries and we give a physical interpretation of the phases that appear. Furthermore, the earlier analytical results for the single-site case are extended to cover multiple-site systems. We also use our exact results to test an efficient numerical algorithm of Giardinà et al (2006 Phys. Rev. Lett. 96 120603), which was developed to measure the current large deviation function directly. We find that this method breaks down in some phases which we associate with the gapless spectrum of an effective Hamiltonian.

We propose exact results for the full counting statistics, or the scaled cumulant generating function, pertaining to the transfer of arbitrary conserved quantities across an interface in homogeneous integrable models out of equilibrium. We do this by combining insights from generalised hydrodynamics with a theory of large deviations in ballistic transport. The results are applicable to a wide variety of physical systems, including the Lieb-Liniger gas and the Heisenberg chain. We confirm the predictions in non-equilibrium steady states obtained by the partitioning protocol, by comparing with Monte Carlo simulations of this protocol in the classical hard rod gas. We verify numerically that the exact results obey the correct non-equilibrium fluctuation relations with the appropriate initial conditions.