Micro-Raman spectroscopy was applied to the study of multiple layered wall paints from the Rosalila temple, Copan, Honduras, which dates to the Middle Classic period (A.D. 520 to 655). Samples of red, green and grey paint and a thick white overcoating were analysed. The paint pigments have been identified as hematite, celadonite or green earth and a combined carbon/mica mixture. By combining Raman spectroscopy with micro-ATR infrared spectroscopy and environmental scanning electron microscopy (ESEM), a detailed study has been made of the materials and processes used to make the stucco and paints. The use of green earth as a green pigment on Maya buildings has not been reported before. The combination of carbon and muscovite mica to create a reflective paint is also a novel finding.
A combination of micro‐Raman spectroscopy, micro‐infrared spectroscopy and SEM–EDX was employed to characterize decorative pigments on Classic Maya ceramics from Copán, Honduras. Variation in red paint mixtures was correlated with changing ceramic types and improvements in process and firing techniques. We have confirmed the use of specular hematite on Coner ceramics by the difference in intensities of Raman bands. Different compositions of brown paint were correlated with imported and local wares. The carbon‐iron composition of the ceramic type, Surlo Brown, was confirmed. By combining micro‐Raman analysis with micro‐ATR infrared and SEM–EDX, we have achieved a more comprehensive characterization of the paint mixtures. These spectroscopic techniques can be used non‐destructively on raw samples as a rapid confirmation of ceramic type.
Micro-Raman spectroscopy has been applied to painted stucco samples from three buildings at the Maya site of Copan, Honduras. The buildings, Clavel (AD 450e550), Ani (AD550e650) and Structure 10L-22 (AD730,) date from three phases of the Classic Period (AD400e820) acropolis construction. The red pigment has been identified as haematite and the stucco as a mixture of calcite particles dispersed throughout a calcite based lime wash stucco. The physical structure of the stucco changed through time, indicating a refining of production techniques over this period. By combining Micro-Raman spectroscopy with other micro-ATR infrared spectroscopy and environmental scanning electron microscopy a detailed investigation of the materials and production techniques used to decorate these buildings has been made. Differences in the mineralogy of the red pigment used on each building indicate a different geological pigment source for each period.
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