BackgroundLiming agricultural land is essential to optimise crop yield and soil nutrients. Despite the importance of pH management in agricultural soils, liming applications have been decreasing in the United Kingdom for decades. There is no comparison of contemporary and historical liming requirement (LR) methods for Northern European, temperate climate mineral soils high in organic matter (OM).AimsThe aims of this research were to thoroughly comparatively analyse current methodologies and to ascertain which soil characteristics contribute to LR reactions.MethodsAnalysis compared methods for determining liming values common in the United Kingdom (Scottish Agricultural College [SAC] look‐up chart, RothLime model), Europe and the United States (Shoemaker–McLean–Pratt, Sikora, Modified Mehlich buffers), and the 30‐min calcium hydroxide titration developed by the University of Georgia.ResultsRothLime and SAC highly underestimated the LR value in acidic soils. The buffers highly over or underestimated LRs. The UGA titration method is a cheap, easy and accurate method which could be utilised for high OM soils but requires further calculation development. The characteristics most associated with soil–lime reactions in this experiment were measures of exchangeability (cation exchange capacity and loss on ignition, and by proxy, lime buffering capacity).ConclusionsThere is an opportunity to create buffer calculators and titration equations adapted to high OM soils. These are suggested for further development, through a larger diversity of UK soil types grouped by buffering capacity ranges. Including soil exchangeability factors in lime management calculations may contribute to more accurate values and therefore better resource management. Increasing LR accuracy for site‐specific soil pH management, used in precision agriculture technologies, is a necessary tool for the conservation of natural resources like limestone, managing resource use efficiency, and for optimising yields.
Agricultural lime is an important natural resource for changing soil pH values. Annual lime applications in the UK have fallen for decades. Estimating soil factors that contribute to the retention and losses of lime would be useful for farmers making resource decisions. The aim of this research was to analyse the soil factors contributing to leaching loss and retention of agricultural lime in Scottish grassland soils. This research also tested the applicability of a large centrifuge method for measuring leached solutions from soil, suggested as an alternative to leaching columns. The soils studied in this research were highly variable in their response to lime. Measures of soil exchange capacity (cation exchange capacity, lime buffering capacity and organic matter) and clay content were highly associated factors to calcium loss and retention within a soil. Suggestions to farmers include consideration of soil clay content, organic matter content (as expressed through C) and cation exchange capacity as factors in lime decision making. Higher exchange capacity soils lost more calcium, likely due to the greater liming requirement of these soils and potential increased excess calcium applied. It is suggested that methods for improving calcium exchange and soil uptake be explored for improving lime retention after liming events.
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