Different characterization techniques were used to analyse the chemically activated carbons in (i) one dimensional analysis including MIP and BET, (ii) two dimensions including SEM and TEM and (iii) three dimensional X-ray CT. This structure has been directly linked to the electrochemical performance of supercapacitors for the first time.
Effective
fabrication of electrocatalysts active in anchoring and
converting lithium polysulfides is critical for the manufacturing
of high-performance lithium–sulfur batteries (LSBs). In this
study, original Fe3O4 nanospheres with diameters
close to 12 nm were finely dispersed over a porous nitrogen-doped
carbon matrix by the freeze-drying method to produce a three-dimensional
composite material (nano-Fe3O4/PNC) suitable
for application as a sulfur host in LSBs. Nano-Fe3O4/PNC loaded with sulfur (S@nano-Fe3O4/PNC) was used as a cathode in a Li–S cell, whose initial
discharge specific capacity reached 1256 mA h g–1 at a 0.1 C rate. After 100 charge–discharge cycles at a 0.2
C rate, the reversible capacity of S@nano-Fe3O4/PNC remained at 745 mA h g–1, demonstrating a
capacity retention rate of 70%. Importantly, a high Coulombic efficiency
of more than 99% was achieved, indicating effective inhibition of
the polysulfides’ “shuttle effect” by nano-Fe3O4/PNC. The use of electrolytes containing lithium
nitrate further reduces the “shuttle effect” of polysulfides.
This study demonstrates the synergistic effect between metal oxide
nanoparticles and N-doped carbon, which plays an important role in
promoting the adsorption and conversion of polysulfides in LSBs.
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