Most of the discovered high-temperature geothermal energy systems are often related with granite that is characterized by natural faults, fractures and cracks of different size. However, the porosity and permeability of the granite matrix is very low, greatly limiting the efficiency of heat extraction in granitic rock. Chemical stimulation, which is regarded as one of the most important means of reservoir stimulation, has consequently received more and more attention. In this paper, a Triassic granite obtained from the eastern region of Liaoning Province in China was reacted with three different concentration of mud acid solution (8% HCl + 1% HF, 10% HCl + 2% HF, 12% HCl + 3% HF) and the resulting microstructure changes studied by scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR). The experimental results show that the number of micropores in the granite increases after chemical corrosion by mud acid solution. A higher mud acid solution concentration results in a much higher pore volume. Triaxial compression tests on the granite before and after chemical corrosion were carried out to study the effect of acidification on the mechanical characteristics of granite, showing that the peak stress and elastic modulus of granite decreases 25.7% and 16.5%, respectively, after exposure to mud acid solution (12% HCl + 3% HF) corrosion for three weeks at room temperature. The particle flow program PFC2D based on discrete element method was used to investigate the mechanical response before and after the chemical corrosion. Considering that the granite is rich in microcracks, the study is simplified by considering them all grouped into one main closed fracture. The influences of main crack inclination angle, crack length, friction coefficient and confining pressure on the mechanical response were investigated. Under the triaxial compression loading state, wing cracks appear at the initial crack tip, then secondary cracks begin to appear. The sensitivity analysis shows that three characteristic strengths (crack initiation strength, damage strength and peak strength) are strongly correlated with crack length, crack inclination angle, crack surface friction coefficient and confining pressure. These three characteristic strengths decrease 60%, 59% and 53%, respectively, compared with their initial values with the increase of main crack length from 6 mm to 22 mm, while they present positive correlation with the fracture friction coefficient from 0 to 1.0 and confining pressure from 10 to 50 MPa. There is a critical inclination angle of the main crack (i.e., 45°), meaning that these three characteristic strengths of granite decrease with inclination angles smaller than 45°, while they increase with an inclination angle larger than 45°. After the corrosion effect of mud acid solution on granite, the pore structure was changed and mechanical properties was damaged, which further affect the failure mode and failure process of granite samples affected by mud acid solutions. This paper provides a theoretical reference for evaluating the effect of chemical stimulation technology on the mechanical characteristics of granite, serving for the continuous hydraulic stimulation design after the chemical stimulation.
The large scale extraction of geothermal energy can reduce CO2 emissions. For hot dry rocks, the key to successful utilization depends on the efficiency of reservoir reconstruction. The chemical and thermal stimulation methods are always used in geothermal reservoir reconstruction except in hydraulic fracturing with high fluid injection pressure, which is believed to reduce the seismic hazard by applying before the high-pressure hydraulic fracturing stimulation. However, at the laboratory scale, there are still very limited experimental studies illustrating the combined effects of chemical and thermal stimulation on the permeability and mechanical properties of granite, which is regarded as the main type of hot dry rock. In this paper, comparative stimulation experiments were carried out, including thermal/cold stimulation, CO2 bearing solution hydro-chemical stimulation, combined thermal and CO2 bearing fluid stimulation. By means of nuclear magnetic resonance analysis, permeability test and triaxial compression test, the changes of the micro-structure, permeability and mechanical properties of granite under various stimulation conditions were analyzed. The experimental results show that, compared with the single thermal stimulation and CO2 bearing fluid hydro-chemical stimulation, the superposition effect of thermal and CO2 bearing fluid hydro-chemical stimulation can increase the number of micro-fractures in granite more effectively, thus increasing the permeability, while the elastic modulus and compressive strength decrease. Moreover, the cooling mode on the granite also has a certain influence on the stimulation effect. After water-cooling on the heated granite (300 °C), combined with the CO2 bearing fluid stimulation (240 °C, 20 MPa), the permeability of granite is the highest, increasing by 17 times that of the initial state, and the porosity also increases by 144.4%, while the elastic modulus and compressive strength decrease by 14.3% and 18.4%, respectively. This implies that the deterioration of mechanical properties due to the micro-fractures increased by the thermal and chemical stimulation can enhance the fluid conductivity and heat extraction of granite. The methods in this paper can provide a reference for the combined application of thermal and chemical stimulation technology in artificial reservoir reconstruction of hot dry rocks.
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