The space environment raises many challenges for new materials development and ground characterization. These environmental hazards in space include solar radiation, energetic particles, vacuum, micrometeoroids and debris, and space plasma. In low Earth orbits, there is also a significant concentration of highly reactive atomic oxygen (AO). This Progress Report focuses on the development of space‐durable polyimide (PI)‐based materials and nanocomposites and their testing under simulated space environment. Commercial PIs suffer from AO‐induced erosion and surface electric charging. Modified PIs and PI‐based nanocomposites are developed and tested to resist degradation in space. The durability of PIs in AO is successfully increased by addition of polyhedral oligomeric silsesquioxane. Conductive materials are prepared based on composites of PI and either carbon nanotube (CNT) sheets or 3D‐graphene structures. 3D PI structures, which can expand PI space applications, made by either additive manufacturing (AM) or thermoforming, are presented. The selection of AM‐processable engineering polymers in general, and PIs in particular, is relatively limited. Here, innovative preliminary results of a PI‐based material processed by the PolyJet technology are presented.
Polyimides (PIs) have been praised for their high thermal stability, high modulus of elasticity and tensile strength, ease of fabrication, and moldability. They are currently the standard choice for both substrates for flexible electronics and space shielding, as they render high temperature and UV stability and toughness. However, their poor thermal conductivity and completely electrically insulating characteristics have caused other limitations, such as thermal management challenges for flexible high-power electronics and spacecraft electrostatic charging. In order to target these issues, a hybrid of PI with 3D-graphene (3D-C), 3D-C/PI, is developed here. This composite renders extraordinary enhancements of thermal conductivity (one order of magnitude) and electrical conductivity (10 orders of magnitude). It withstands and keeps a stable performance throughout various bending and thermal cycles, as well as the oxidative and aggressive environment of ground-based, simulated space environments. This makes this new hybrid film a suitable material for flexible space applications.
The combined effect of hypervelocity space debris impact and atomic oxygen (AO) attack on the degradation of reinforced polyhedral oligomeric silsesquioxanes (POSS)-polyimide films was studied. A laser-driven flyer (LDF) system was used to accelerate aluminum flyers to impact velocities of up to 3 km s -1. The impacted films were exposed to an RF-plasma source, which was used to simulate the effect of AO in the low Earth orbit. Scanning electron microscopy (SEM) was used to characterize the fracture morphology. The extent of damage in POSS-polyimide impacted films was found to be much smaller compared to POSS-free films, insinuating on a toughening mechanism developed due to POSS incorporation. When exposed to air RF-plasma, the impacted POSS-free film revealed a synergistic effect associated with a large increase in the erosion rate while impacted POSS-containing samples showed improved erosion resistance. The increased erosion rate of the impacted POSS-free film is explained by formation of residual stresses that affect the oxidation mainly by increasing the diffusivity of oxygen.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.