This study aimed to evaluate the use of coagulation/flocculation and Fenton processes for the removal of the recalcitrant component, in particular humic substances, from two different leachates generated in the Gericinó and Gramacho landfills in Rio de Janeiro State (Brazil). A coagulation/flocculation process, using FeCl·6HO as the coagulant, was applied to the two leachate samples. In the case of the leachate from Gericinó landfill, the treatment removed 93% of color, 71% of TOC, 69% of COD, 76% of HS, 73% of humic acids (HA) and 82% of fulvic acids (FA). In addition, there was a 75% reduction in the absorbance at 254 nm, using 3,000 mg L of coagulant. In the case of the leachate from Gramacho landfill, the treatment removed 91% of color, 69% of TOC, 68% of COD, 77% of HS, 75% of HA and 80% of FA. In addition, there was a 70% reduction in the absorbance at 254 nm using the same concentration of coagulant (3,000 mg L). The Fenton processes, using FeSO·7HO and HO in a ratio of 1:5, were also applied to the two leachate samples. In the case of the Gericinó leachate, the Fenton treatment removed 95% of color, 75% of TOC, 68% of COD, 82% of HS, 77% of HA and 93% of FA. In addition, there was a 93% reduction in the absorbance at 254 nm. In the case of the Gramacho leachate, the Fenton treatment removed 93% of color, 73% of TOC, 71% of COD, 81% of HS, 76% of HA, 90% of FA, and there was an 84% reduction in the absorbance at 254 nm. The results of humic substances, color, organic matter and aromatic organic matter (absorbance at 254 nm) demonstrate that the coagulation/flocculation and Fenton processes were efficient in the removal of recalcitrant organic matter from landfill leachates.

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The leachate treatment by nanofiltration (NF) process has received much attention over the last two decades. Previous studies focused on the investigation of the technical feasibility of NF. However, there are a limited number of works that examined leachate treatment costs. On the other hand, in a landfill management system, the economic component is an imperative factor for the decisions of all operations. Thereby, this work aimed to investigate the technical feasibility and economic parameters involved in a full-scale NF plant for the treatment of leachate previously treated by the physicochemical process. The average quality of the pre-treated leachate was 2258 ± 230 mg L−1 chemical oxygen demand (COD) and 821 ± 86 mg L−1 humic substances (HS). NF was performed using a bench-scale filtration module with commercial polymeric membranes SR100 and NP030. At the end of each filtration, a cleaning protocol was applied to recover the initial membrane permeability. The concentration of recalcitrant compounds, expressed as HS, was reduced to 84 ± 8 mg L−1 in the permeate, and COD complies with the wastewater discharge standards imposed by local legislation. The capital costs for a full-scale NF was estimated at MUS$ 0.772, and specific total cost, treated leachate per volume unit, has been estimated at US$ 8.26 m−3.

The 2019–2020 coronavirus pandemic imposed unprecedented challenges in Brazilian governance sectors, mostly in the waste management system. Herein, we analyse the main challenges of the recycling sector in Brazil to cope with this scenario. Understanding difficulties during the pandemic outbreak of COVID-19 can help improve waste recycling in the post-pandemic period in Brazil and other developing nations that face similar issues. The current pandemic exposed the deficiencies of this system, and some important lessons can be learned. Recommendations are drawn to advance the proper management of recyclables in the country. The Government must increase total investments in the recycling industry's infrastructure and support local recycling initiatives during a public health crisis and beyond. In sum, this paper strengthens the idea that waste segregation at the source and selective collection will not be sufficient without massive investments in the recycling sector’s infrastructure. The future challenge includes strengthening the economic markets for recycled materials. Graphic abstract