Using carbon free energy sources is one of the keys to mitigate climate change. Hydrogen promises to be one of these carbon free energies, but its storage is difficult and expensive. Ammonia, however, is interesting as it can store hydrogen safely and can be used in combustion engines instead of hydrocarbon fuels. In this experimental work, the spray characteristics of ammonia under different air densities and temperatures were investigated in constant volume and were compared to a biofuel, ethanol, and a common fuel, gasoline. The Schlieren technique was used to capture images of liquid and liquid + vapor spray. The penetration length, the angle near the injector and the angle at half-penetration length were measured. The results show that the spray geometry of ammonia differs from that of the other fuels and that its sensitivity to air density and temperature is greater. The flash boiling condition at ambient temperature was explored for ammonia and indicated a wider spray at half-penetration length at phase change. Moreover, a semi-empirical correlation for penetration length as a function of physical parameters was found with a high accuracy for the global spray. These experimental data provide the first information about ammonia injection with a current spark-ignition GDI injector.
Combustion and emissions characteristics of a spark-ignition engine using direct injection of ethanol blended with ammonia and also pure ammonia were investigated in this study. The experiments were conducted using five different fuel compositions of ethanol/ammonia (C2H5OH/NH3): 100/0, 75/25, 50/50, 25/75, and 0/100. Two strategies of injection were conducted to reach homogenous or stratified conditions with three different intake pressures, 0.5, 1.0, and 1.5 bar corresponding to 2.8, 7.9, and 12 bar of IMEP. The performances and the pollutants emissions are compared as a function of fuel compositions at identical IMEP. High stability is observed for all blends and even for pure ammonia. However, operating conditions are more restrictive for pure ammonia: the injection must be executed during the intake phase to be in a fully premixed mode to guarantee engine stability. Delaying the injection time for pure ammonia is not possible and requires the split of injections with 50% of the ammonia amount injected during the intake. The thermal efficiency is improved by adding 25% of NH3 in ethanol but NOx emissions increase. The stratified strategy for blends improves the combustion durations and the addition of ammonia decreases the NOx emission compared to the homogeneous strategy. On the contrary, CO emissions roughly increase for blends. The presence of NH3 in the fuel composition clearly influences the change of formation of NOx and CO between both strategies.
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