Biogas is a renewable energy that has been explored widely in Indonesia to substitute non-renewable energy. However, the presence of certain gas, such as carbon dioxide (CO2), can decrease the calorific value and generate greenhouse gas. Hence, the separation of CO2 from methane (CH4) occurs as a crucial step to improve the utilization of biogas. The separation of CH4/CO2 can be conducted using a polymeric membrane that needs no chemical, hence considered as an environmentally friendly technique. However, the utilization of polymeric membrane in gas separation processes is hampered by the trade-off between gas throughput and selectivity. To solve this problem, the incorporation of inorganic particles, such as Zeolitic Imidazolate Framework-8 (ZIF-8) particles, into the polymer matrix to improve the gas separation performance of the membrane has been conducted recently. In this research, ZIF-8 has been incorporated into Polysulfone matrix to form ZIF-8/Polysulfone-based membrane by simple blending and phase inversion techniques in flat sheet configuration. The pure gas permeation tests showed an increase in gas permeability (26 Barrer compared to 17 Barrer) after the inclusion of ZIF-8 particles with a slight decrease in CO2/CH4selectivity for particle loading more than 15wt. %. Therefore, the membrane with 15wt. % of particles showed the best performance in terms of gas selectivity. This result was due to the aggregation of ZIF-8 particles at particle loading higher than 15wt. %. Chemical analysis indicated an interaction between filler and polymer, and there were increases in the degree of crystallinity after the incorporation of ZIF-8.
Recently, small scale fashion industries are growing quite rapidly in Indonesia. This is due to the continuous encouragement and facilitation by the Government of Indonesia to improve workforce in creative industry. As fashion industries depend on the availability of dyes as one of their resource, it is very important to develop a new and sustainable supply of dyes for dyeing process in fashion industries. Hence, research on the extraction of dyes from sustainable and natural resources for fashion industries are considered very important and urgent. Dyes for fashion and textile are naturally occurred in plants or parts of plants. The extraction of dyes from these sources can be conducted by using simple mixing between solvent and the plants inside a soxhlet extractor or reflux apparatus. In this study, the extraction processes of natural dyes from two materials, i.e. sappanwood, and mango leaf employing combination of maceration, soxhlet and reflux techniques were reported. The experiments were conducted to analyse the effects of extraction time and solvent to materials ratios on the yield of dyes. The experimental results showed that for all materials the optimum ratio of material and solvent was 1 : 6. In addition, the reflux followed by maceration could produce dyes that can be utilised for fabric coloring that suits the industrial needs.
In recent years, due to the massive pollution spread, the switchover to the eco-friendly process is being considered. Particularly, in textile industries, the wastewater containing dangerous substances dangers the condition of the rivers directing to the use of natural dyes. The existing traditional industries often use natural sources with lacks of study about the method and process condition to gain the best quality and the highest quantity of colorants. This study aim is to find the time for the extraction using common materials and simple method resembling the real situation. The common natural dye source, Mangifera indica leaves, particularly from Gadung species – a common type of Mangifera indica in Indonesia – is on this study using reflux method combined with methanol and water as its solvent separately. The steps used is a modification from the preceding process, which includes tannin and fatty acids in the final product. Spectral analysis indicated that the best time for extraction using water, which produces pale yellow color is 60 min, and the best time for extraction using methanol, which produces green color is 360 min. Therefore, the next application of boiling the materials with water can be reduced to the written times above.
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