The transition between the Cassie and Wenzel wetting regimes has been observed under vertical vibration of a water drop placed on a rough micrometrically scaled polymer pattern. The transition takes place under the constant force per unit length of the triple contact line, not under constant pressure. A study of the vibrating drop deposited on the rough surface supplied valuable information concerning the Cassie-Wenzel wetting transition.
The motion of ferrofluidic marbles on flat polymer substrates is reported. Nanopowders of polyvinylidene fluoride and gammaFe2O3 were used for the preparation of ferrofluidic marbles. The marbles are activated easily with an external magnetic field. A microfluidic device based on ferrofluidic marbles (the ferrofluidic bearing) is described. Velocities of marbles as high as 25+/-3 cm/s were registered. The sliding of ferrofluidic drops on superhydrophobic surfaces was studied. It was demonstrated that the threshold magnetic force necessary for the drop displacement depends linearly on the drop radius, thus the motion of the drop is defined by the processes occurring in the vicinity of the triple line only.
A superhydrophobic surface is produced from industrial grade polymer materials. The surface comprises partly disordered triple-scaled arrays of polyvinylidene fluoride (PVDF) globules. An inherently superhydrophobic metallic surface is produced with polymer template. The mathematical model based on the Cassie-Baxter hypothesis of air trapping under a water drop is built, which gives the apparent contact angle on the manifold-scaled interface. The presence of several scales itself is not a sufficient condition of hydrophobicity of inherently wettable surfaces. The geometrical features favoring the increase of the vapor-water interface fraction are necessary for this phenomenon.
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