Finely dispersed copper nanoparticles were added as an additive to fully-formulated engine oils. The copper additive was in colloidal form, with an inner core of Cu 2+ atoms covered by surfactants to form stable reverse micelles that are completely dispersible in the base oil. The tribological process to form protective films at the metal surface is comprised of three phases. Phase I can be considered a physical process involving the build-up of polar molecules by absorption to produce a friction modifier film, whereas phases II and III have to be treated as mechanochemical processes comprising a combination of redox reactions and a third body formation. The tribological performance was investigated using atomic force microscopy, a microtribometer, a pin-on-disk tribometer in combination with continuous and high-resolution wear measurements with radionuclide technique, and high pressure stressing in a thrust roller bearing test rig. In addition, the nanostructure of the additive was characterized by atomic force microscopy. Finally, the chemical composition of the metal surface was analyzed using photoelectron spectroscopy.
An ultra-thin water film plays the decisive role in steel-ice friction in bobsleighing. The water film has a thickness on the order of nanometers and results from the superposition of an existing quasi-liquid layer and additional surface water generated by frictional heat. When friction is measured as function of sliding velocity, the coefficients decrease according to the typical Stribeck behavior. However, for highest sliding velocities, it is still unknown whether friction decreases further or shows an increase due to viscous drag. Both tendencies are essential for the construction of safe bobsleighs and bobsleigh tracks. This contribution presents results of high-speed experiments up to 240 km/h for a steel slider on a disk of ice at different ice temperatures. In addition, using the friction model of Makkonen, friction coefficients were calculated as function of sliding velocity and ice temperature. The significant correlation between experimental results and model calculation supports the model conception of frictional melting and viscous shearing.
Using a high-speed tribometer, coefficients of friction for bobsled runners were measured over a wide range of loads and speeds. Between 2.8 m/s and 28 m/s (equal to 10 km/h and 100 km/h), the measured coefficients of friction showed a linear decrease with increasing speed. e experiments revealed ultra-low friction coefficients of less than 0.01 aer exceeding a sliding speed of about 20 m/s. At maximum speed of 28 m/s, the average coefficient of friction was 0.007. e experiments help to bridge the gap between numerous low-speed friction tests by other groups and tests performed with bobsleds on real tracks. It was shown that the friction data obtained by other groups and our measurements can be approximated by a single master curve. is curve exhibits the largest decrease in friction up to a sliding speed of about 3 m/s. e further increase in speed generates only a small decrease in friction. In addition, friction decreases with increasing load. e decrease stops when ice wear becomes effective. e load point of constant friction depends on the cross-sectional radius of the runner. e larger the radius is, the higher the load is, before the ice shows signs of fracture. It turned out that besides aerodynamic drag (not considered in this work), ice friction is one of the main speed-limiting factors. In terms of runner geometry, a �at contact of runner and ice ensures the lowest friction. e rocker radius of the runner is of greater importance for a low coefficient of friction than the cross-sectional radius.
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