We have studied porphyritic olivine-rich chondrules of the carbonaceous chondrite Kaba (CV3) by combined highresolution X-ray mapping, quantitative electron microprobe analyses, and oxygen isotopic analyses via secondary ion mass spectrometry. These chondrules contain smaller inner-chondrule olivine grains characterized by low refractory element (Ca, Al, Ti) contents, and larger outer-chondrule olivine crystals that are enriched in refractory elements and show complex Ti and Al oscillatory zonings. Our O isotopic survey revealed that many of the inner-chondrule olivines are 16 O-richer than the relatively isotopically uniform outer-chondrule olivines. Inner-chondrule olivine crystals-only a minority of which may be derived from earlier generations of chondrules-are likely mostly inherited from nebular condensates similar to AOAs, as they share similar isotopic and chemical features and are thus interpreted as relict grains. Still, being 16 O-poorer than most AOAs, they may have experienced significant exchange with a 16 O-poor reservoir prior to chondrule formation (even if to a lesser degree than relicts in CM2 and ungrouped C2 chondrites). Subsequent incomplete melting of the relict grains produced Ca-Al-Ti-rich melts that engulfed the remaining relict olivine grains. The complex Ti and Al zoning patterns in outer chondrule (host) olivines, in particular the systematic dilution near the margin, seem to reflect gas-melt interactions (with e.g. SiO (g), Mg (g)) which also buffered the O isotopic composition of chondrule hosts. Together, these results demonstrate that important episodes of recycling of nebular condensates occurred in the solar protoplanetary disk.

<p>The leading hypotheses proposed to explain the rise in atmospheric CO2 during the last glacial to interglacial transition proposes enhanced carbon transfer from the intermediate and deep oceans to the atmosphere via the intensification of southern ocean upwelling. To test this scenario, we generated a high resolution record of boron isotopes (d<sup>11</sup>B) and B/Ca (proxies for pH and carbonate ion concentration, respectively) measured on shells of the benthic foraminifera C. wuellestorfi from a marine sedimentary core located at intermediate depth (1536m) on the Chilean margin. Our records confirm the link between changes in ocean circulation and variations in the carbonate chemistry at this site. The data also reveal the increase of intermediate water pH at the very late LGM, before the beginning of the deglaciation and the rise in atmospheric pCO<sub>2</sub>. To account for this observation, we suggest the existence of an early release of carbon from the intermediate ocean to the atmosphere in response to sea ice retreat occurring at the same time. The lack of any clear increase in atmospheric CO2 suggests that this release of intermediate ocean carbon was compensated by enhanced biological pumping.</p>

<p>Vertical and lateral exchanges of heat and carbon make the Southern Ocean a key player in regulating global climate, yet its role in future climate change remains uncertain. To address this knowledge gap, paleoceanographers study the state of the Southern Ocean under past climate states to better understand the processes governing its role in global climate. For instance, the Southern Ocean is widely thought to play a driving role in the atmospheric CO<sub>2</sub> fluctuations of the ice ages, ventilating carbon-rich deep waters to the atmosphere during interglacial periods and limiting this deep-surface exchange during glacial periods. However, direct evidence of these dynamics and of the Southern Ocean’s overall role in glacial CO<sub>2</sub> draw down remains limited.</p><p>Here we present a suite of geochemical data that provides new insights into Southern Ocean carbon cycling and circulation, evincing deep-ocean carbon storage over the last glacial cycle. Trace element and stable isotope (δ<sup>13</sup>C, δ<sup>18</sup>O) compositions of foraminiferal calcite from the high-latitude Indian Ocean demonstrate how carbon was sequestered in the deep ocean during glacial intensification and subsequently released to surface waters during deglaciation. These dynamics are captured by geochemical records reflecting temperature, pH, and circulation changes, providing key insights into the processes responsible for this carbon cycling. This observational data provides the foundation for developing a better mechanistic understanding of the Southern Ocean’s role in past and future climate change, including processes such as advection and mixing, ocean-ice interactions, and productivity.</p>