From coüiisionai activation data it is concluded that the non-decomposing [IMH-H,O]+ ions from both cis-and trans-1,Z-cyclohexanediol possess the structnre oí protonated cyclopentanecarboddehyde. "he mechanism of this process as weil as alternatives are discussed.StoBaktivierungsspektren legen den SchluB nahe, da8 die H20-Abspaltung aus protoniertem cis-und trans-1,2-Cyclohexandiol zum protonierten Cyclopentylcarbaldehyd fiihrt. Der Mechanismus dieser und alternativer Reaktionen wird diskutiert. t Korrespondenzautoren.
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