Multi-elemental (Ca, Mg, Na, K, Al, As, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, P, Pb, Sb, Se, Tl, V, and Zn) and stable isotope (i.e., δ2H, δ18O, and δ13CDIC) analyses were performed on 13 (8 Slovenian and 5 imported) bottled mineral and spring waters from the Slovenian market. In addition, 87Sr/86Sr isotope ratios were determined for the first time. In all analyzed bottled waters, the majority of elements were present although in low concentrations, and according to EU legislation, all were suitable for human consumption. Also, concentrations of major elements (Ca, Mg, Na, and K) were in general agreement with the values reported on the bottle labels, and any differences were the consequence of the natural variability of the water source used for bottling. The exception was one spring water, for which the source location changed, which was confirmed by the δ2H, δ18O, and δ13CDIC data. Two mineral waters had distinctive elemental compositions due to the particular geology of their recharge areas. The δ13CDIC was also investigated to decipher the carbonate contribution in the bottled waters. The results suggest that dissolution of carbonates and non-equilibrium carbonate dissolution by carbonic acid produced from soil zone CO2 are the predominant geochemical processes influencing the δ13CDIC values of bottled water.
In this paper, we summarise lessons learned conducting citizen science (CS) activities within the CitieS-Health H2020 project on the topic of noise exposure and health at a primary school in Ljubljana, Slovenia. Activities were organised in the form of a School Tech-Day Event (STDE) as part of the school’s curriculum involving second-grade pupils, ages 7–8. The STDE was aligned with the project’s methodological framework, which is based on co-creation and co-design principles. To this end, the pupils initially were involved in identifying noise-related issues and translation of selected topics into research questions. Next, together with mentors, they participated in the process of hypothesis formulation and the designing of data collection protocols. Finally, they participated in three focussed noise measurement experiments, as well as data analysis and presentation. We report and critically evaluate the whole chain of activities, focussing on the participant dimension using selected components of the citizen science evaluation framework. The event was very well-received by both pupils and teachers, and their active participation and hands-on experience with scientific processes contributed to their improved scientific literacy. Overall, the demonstrated concept of CS activities has great potential for ongoing inclusion in the school curriculum in its current format, or else adjusted according to specifics from other science and technology fields.
Low-cost sensors can be used to improve the temporal and spatial resolution of an individual’s particulate matter (PM) intake dose assessment. In this work, personal activity monitors were used to measure heart rate (proxy for minute ventilation), and low-cost PM sensors were used to measure concentrations of PM. Intake dose was assessed as a product of PM concentration and minute ventilation, using four models with increasing complexity. The two models that use heart rate as a variable had the most consistent results and showed a good response to variations in PM concentrations and heart rate. On the other hand, the two models using generalized population data of minute ventilation expectably yielded more coarse information on the intake dose. Aggregated weekly intake doses did not vary significantly between the models (6–22%). Propagation of uncertainty was assessed for each model, however, differences in their underlying assumptions made them incomparable. The most complex minute ventilation model, with heart rate as a variable, has shown slightly lower uncertainty than the model using fewer variables. Similarly, among the non-heart rate models, the one using real-time activity data has less uncertainty. Minute ventilation models contribute the most to the overall intake dose model uncertainty, followed closely by the low-cost personal activity monitors. The lack of a common methodology to assess the intake dose and quantifying related uncertainties is evident and should be a subject of further research.
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