Hole transporting layer plays a crucial role to realize high efficiency and long lifespan by balancing the charge carrier into the desired recombination zone.
Organic light emitting diodes (OLEDs) have been well known for their potential usage in the lighting and display industry. The device efficiency and lifetime have improved considerably in the last three decades. However, for commercial applications, operational lifetime still lies as one of the looming challenges. In this review paper, an in-depth description of the various factors which affect OLED lifetime, and the related solutions is attempted to be consolidated. Notably, all the known intrinsic and extrinsic degradation phenomena and failure mechanisms, which include the presence of dark spot, high heat during device operation, substrate fracture, downgrading luminance, moisture attack, oxidation, corrosion, electron induced migrations, photochemical degradation, electrochemical degradation, electric breakdown, thermomechanical failures, thermal breakdown/degradation, and presence of impurities within the materials and evaporator chamber are reviewed. Light is also shed on the materials and device structures which are developed in order to obtain along with developed materials and device structures to obtain stable devices. It is believed that the theme of this report, summarizing the knowledge of mechanisms allied with OLED degradation, would be contributory in developing better-quality OLED materials and, accordingly, longer lifespan devices.
Abundant molecules enable countless combinations of device architecture that might achieve the desirable high efficiency from organic light-emitting diodes (OLEDs). Due to the relatively high cost of OLED materials and facilities, simulation approaches have become a must in further advancing the field faster and saver. We have demonstrated here the use of state-of-art simulation approaches to investigate the effect of molecular orbital energy levels on the recombination of excitons in OLED devices. The devices studied are composed of 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) as hole transporting material (HTM), 4,4′-Bis(9-carbazolyl)-1,1′-biphenyl (CBP) as host, 2,2',2”-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) or bathophenanthroline (Bphen) as electron transporting materials. The outcomes reveal that exciton recombination highly sensitive to the energy-level alignment, injection barriers, and charge mobilities. A low energy-barrier (<0.4 eV) between the layers is the key to yield high recombination. The lowest unoccupied molecular orbital (LUMO) levels of the organic layers have played a more pivotal role in governing the recombination dynamics than the highest occupied molecular orbital (HOMO) level do. Furthermore, the Bphen based device shows high exciton recombination across the emissive layer, which is >106 times greater than that in the TPBi based device. The high carrier mobility of Bphen whose electron mobility is 5.2 × 10−4 cm2 V−1 s−1 may lead to low charge accumulation and hence high exciton dynamics. The current study has successfully projected an in-depth analysis on the suitable energy-level alignments, which would further help to streamline future endeavours in developing efficient organic compounds and designing devices with superior performance.
A novel
design of aggregation-induced emission (AIE) active columnar
(Col) luminomesogens is reported, and they are demonstrated to act
as highly efficient deep-blue emitters in organic light-emitting diodes
(OLEDs). All derivatives exhibit Col liquid crystalline (LC) behavior
at room temperature over a wide temperature range and desirable alignment
properties, which is very important in using them as materials for
organic electronic devices. These new AIE active luminomesogens were
found to act as highly efficient emitters in OLEDs and unveiled a
maximum external quantum efficiency of 4.0% for the first time in
Col LCs with Commission International de l’E’clairage
coordinates of (0.17, 0.07), which closely matches the National Television
System Committee (NTSC) standard, corresponding to pure deep blue
color. The detailed supramolecular assembly of the compounds has been
characterized by modeling in the mesophase derived from small- and
wide-angle X-ray scattering results.
Transforming triplet excitons to singlet excitons is a topic of great interest to material scientists in order to surpass the exciton utilization efficiency (EUE) limit of 25 % in electro-fluorescent...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.