This study develops an approach based on hierarchical cluster analysis for investigating the spatial and temporal variation of water quality governing processes. The water quality data used in this study were collected in the karst aquifer of Yucatan, Mexico, the only source of drinking water for a population of nearly two million people. Hierarchical cluster analysis was applied to the quality data of all the sampling periods lumped together. This was motivated by the observation that, if water quality does not vary significantly in time, two samples from the same sampling site will belong to the same cluster. The resulting distribution maps of clusters and box-plots of the major chemical components reveal the spatial and temporal variability of groundwater quality. Principal component analysis was used to verify the results of cluster analysis and to derive the variables that explained most of the variation of the groundwater quality data. Results of this work increase the knowledge about how precipitation and human contamination impact groundwater quality in Yucatan. Spatial variability of groundwater quality in the study area is caused by: a) seawater intrusion and groundwater rich in sulfates at the west and in the coast, b) water rock interactions and the average annual precipitation at the middle and east zones respectively, and c) human contamination present in two localized zones. Changes in the amount and distribution of precipitation cause temporal variation by diluting groundwater in the aquifer. This approach allows to analyze the variation of groundwater quality controlling processes efficiently and simultaneously.
Coastal aquifers are characterized by a mixing zone with freshwater-saltwater interactions, which have a strong relationship with hydrological forcings such as astronomical and storm tides, aquifer recharge and pumping effects. These forcings govern the aquifer hydraulic head, the spatial distribution of groundwater salinity and the saline interface position. This work is an empirical evaluation through time-series analysis between aquifer head and groundwater salinity associated with the sea-level dynamics and the aquifer recharge. Groundwater pressure, temperature and salinity were measured in a confined aquifer in the northwest coast of Yucatan (México) during May 2017-May 2018, along with precipitation. Cross-correlation and linear Pearson correlation (r) analyses were performed with the data time series, separating astronomical and meteorological tides and vertical recharge effects. The results show that the astronomical and meteorological tides are directly correlated with the aquifer head response (0.71 < r < 0.99). Salinity has a direct and strong relationship with the astronomical tide (0.76 < r < 0.98), while the meteorological tide does not (r < 0.5). The vertical recharge showed a moderate correlation with the aquifer head (0.5 < r < 0.7) and a nonsignificant correlation with the groundwater salinity (r < 0.5). In this study, the sea level (r > 0.7) is a more important forcing than the vertical recharge (with 0.5 < r < 0.7). Empirical relationships through time-series analysis and the separation of individual hydrological forcings in the analysis are powerful tools to study, define and validate the conceptual model of the aquifer.
The Ring of Cenotes (RC) extends along the edge of the Chicxulub crater, in the limestone platform of the Yucatan Peninsula (YP), where groundwater shows two preferential flow paths toward the coast near Celestun and Dzilam Bravo towns. The objectives of this study were to describe the regional hydrogeochemical evolution of the groundwater in the RC, and its association with the dissolution/precipitation of the minerals present along its pathway to the ocean. These objectives results were obtained by: a) characterizing groundwater hydrogeochemistry; b) calculating calcite, dolomite, and gypsum saturation indexes in the study area; and c) developing a hydrogeochemical model using PHREEQC (U. S. Geological Survey) inverse modelling approach. The model predictions confirmed that there are two evolution pathways of the groundwater consistent with the preferential flow paths suggested in a previous regionalization of the RC. On the western path, where groundwater flows towards Celestun, marine intrusion influences the hydrogeochemical processes and represents a risk for the freshwater. On the eastern path, where groundwater flows toward Dzilam Bravo, rainfall has an important effect on the hydrogeochemical processes, evidenced by a higher concentration in sulfates during droughts than during rainy periods. Then, monitoring of marine intrusion and phases dissolution in the RC is highly recommended
Springs are common features on the Yucatán coast. They can discharge either under the sea (submarine) or inland in coastal lagoons and wetlands. Previous observations of a coastal lagoon located on the northern Yucatán Peninsula (La Carbonera) reported sea water intrusion on a spring that discharge on a coastal lagoon (lagoon tidal spring). The saltwater intrusion occurs when the tide is at its lower level, which is the opposite to what has been reported for submarine springs in the Yucatán Peninsula. In this study, the hydrodynamics of the spring is analyzed and the driving forces controlling the seawater intrusion are identified and discussed. Time series of water levels, salinity, and velocity measurements in the lagoon, the aquifer, and the spring are analyzed by means of tide component decomposition and cross-correlations analysis of the tide signals. Results show that the main driving forces causing the intrusion are the density differences and pressure head gradients, and the mechanisms influencing the driving forces driving those differences are the tides, the friction in the lagoon, and the confinement of the aquifer; other mechanisms are discussed to present a complete idea of the complexity of the interactions between the coastal aquifer, the coastal lagoons, and the sea.
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