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The equilibrium constants for the formation of inclusion complexes of a-and d-cycloamylose with small anions were measured using conductance methods. For the series of anions, C104-, SCN-, I-, Br-, and NO3-, the association constants for complexes with -cycloamylose are 28.9, 18.7, 12.4, 3.5, and 1.4 M-1. The association constant for SCN-with d-cycloamylose is 9.9 M-1. Cl-, SO42-, and acetate do not bind with a-cycloamylose.

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