Barium
disilicide (BaSi2) has been regarded as a promising absorber
material for high-efficiency thin-film solar cells. However, it has
confronted issues related to material synthesis and quality control.
Here, we fabricate BaSi2 thin films via an industrially
applicable sputtering process and uncovered the mechanism of structure
transformation. Polycrystalline BaSi2 thin films are obtained
through the sputtering process followed by a postannealing treatment.
The crystalline quality and phase composition of sputtered BaSi2 are characterized by Raman spectroscopy and X-ray diffraction
(XRD). A higher annealing temperature can promote crystallization
of BaSi2, but also causes an intensive surface oxidation
and BaSi2/SiO2 interfacial diffusion. As a consequence,
an inhomogeneous and layered structure of BaSi2 is revealed
by Auger electron spectroscopy (AES) and transmission electron microscopy
(TEM). The thick oxide layer in such an inhomogeneous structure hinders
further both optical and electrical characterizations of sputtered
BaSi2. The structural transformation process of sputtered
BaSi2 films then is studied by the Raman depth-profiling
method, and all of the above observations come to an oxidation-induced
structure transformation mechanism. It interprets interfacial phenomena
including surface oxidation and BaSi2/SiO2 interdiffusion,
which lead to the inhomogeneous and layered structure of sputtered
BaSi2. The mechanism can also be extended to epitaxial
and evaporated BaSi2 films. In addition, a glimpse toward
future developments in both material and device levels is presented.
Such fundamental knowledge on structural transformations and complex
interfacial activities is significant for further quality control
and interface engineering on BaSi2 films toward high-efficiency
solar cells.
Abstract:We have used 3-D optical modelling to investigate light management concepts based on periodic textures and material optimization for photovoltaic devices based on Cu(In,Ga)Se 2 (CIGS) absorber material. At first, calibration of the software based on the characterization of a reference (1500-nm thick) CIGS device was carried out. The effects of 1-D and 2-D symmetric gratings on the cell were then investigated, showing significant improvement in anti-reflection effect and in absorptance in the active layer, achieved by excitation of guided modes in the absorber. In addition, device configurations endowed with alternative back reflector and front transparent conductive oxide (TCO) were tested with the goal to quench parasitic absorption losses at front and back side. The use of In 2 O 3 :H (IOH) as front and back TCO, combined with an optimized 2-D grating structure, led to a 25% increase of the optical performance with respect to an equally-thick flat device. Most of the performance increase was kept when the absorber thickness was reduced from 1500 nm to 600 nm.
Abstract:We present the optical investigation of a novel back-contacted architecture for solar cells based on a thin barium (di)silicide (BaSi 2 ) absorber. First, through the analysis of absorption limits of different semiconducting materials, we show the potential of BaSi 2 for photovoltaic applications. Then, the proposed back contacted BaSi 2 solar cell design is investigated and optimized. An implied photocurrent density of 40.3 mA/cm 2 in a 1-μm thick absorber was achieved, paving the way for novel BaSi 2 -based thin-film solar cells.
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