Mechanoluminescence (ML) is the phenomenon describing the emission of light during mechanical action on a solid, leading to applications such as pressure sensing, damage detection and visualization of stress distributions. In most cases, this mechanical action releases energy that was previously stored in the crystal lattice of the phosphor by means of trapped charge carriers. A drawback is the need to record the ML emission during a pressure event. In this work, we provide a method for adding a memory function to these pressure-sensitive phosphors, allowing an optical readout of the location and intensity of a pressure event in excess of 72 h after the event. This is achieved in the BaSi2O2N2:Eu2+ phosphor, where a broad trap depth distribution essential for the process is present. By merging optically stimulated luminescence (OSL), thermoluminescence (TL) and ML measurements, the influence of light, heat and pressure on the trap depth distribution is carefully analysed. This analysis demonstrates that mechanical action can not only lead to direct light emission but also to a reshuffling of trap occupations. This memory effect not only is expected to lead to new pressure sensing applications but also offers an approach to study charge carrier transitions in energy storage phosphors.

Inorganic barriers grown by atomic layer deposition (ALD) can overcome the stability issues originating from the permeation of foreign species (water and oxygen) into polymer thin films. Alternatively, infiltration of ALD species into the bulk of the polymer can be used to modify its characteristic properties. In this study, the feasibility of growing an inorganic barrier with ALD on polystyrene, poly(methyl methacrylate), and poly(ethylene terephthalate glycol) thin films is evaluated. The nucleation and growth of the ALD layer, including the infiltration into the polymer thin film, are monitored in situ using spectroscopic ellipsometry, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy for Al 2 O 3 -ALD with trimethylaluminum as the Al precursor and H 2 O as the reactant. The results show that the deposition temperature and the presence and location of functional groups in the polymer chain exert the strongest influence on the infiltration behavior and as such allow us to manipulate (i.e. to prevent or expedite) the infiltration into the polymer thin film.

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International audienceThe demand for highly coupled high quality acoustic wave devices for radio-frequency (RF) signal processing based on passive devices has generated a strong innovative activity, yielding the investigation of new excitation principles and waveguide structures. Periodically poled transducers (PPTs) have been recently investigated [E. Courjon et al., J. Appl. Phys. 102, 114107 (2007)], as an alternative to classical interdigital transducers (IDTs) for the excitation and detection of guided acoustic waves. PPTs have two principal advantages compared to IDTs: the robustness of the excitation versus defects or surface contamination and the possibility to excite waves exhibiting a wavelength equal to the poling period. Here a new acoustic resonator concept is suggested, allowing high frequency operation with a simplified package. The idea consists of using a waveguide based on a PPT fabricated on a ferroelectric single-crystal substrate such as lithium niobate or tantalate inserted between two single-crystal substrates allowing the guidance of elastic waves without losses. The concept analysis points out optimum configurations of the structure allowing the excitation of elastic waves compatible with RF applications