The cobalt hexacyanoferrate system, M h [FeB(CN)6] l , (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.

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There are nanotechnology-based materials that can be used as antimicrobial additives in different applications such as water-borne paints. Antimicrobial paints are important tool in order to avoid indoor biological colonization and therefore prevent paint bio-deterioration and health problems in people and pets. These paints would have application in kitchens, bathrooms and hospitals. The present study evaluated the incorporation of silver (of two different sizes), copper and zinc oxide nanoparticles in indoor waterborne paints and the bio-resistance imparted by them. The antifungal activity of nanoparticles is a less studied topic in relation to the antibacterial activity but is no less important from the environmental point of view. Molds that grow in indoor environments contribute significantly with bioaerosol formation and therefore on air contamination and human health deterioration. In this sense, this research evaluated the nanoparticles' antifungal activity using previously isolated fungi, Chaetomium globosum and Alternaria alternata, on solid medium. Then, the bio-resistance of acrylic paints, with nanoparticles incorporated, was evaluated in Petri dishes and observations were made using scanning electron microscopy. The better results were obtained with the paint that contained silver with the smaller size (10 nm).

Microbial growth in indoor environments creates health problems, especially in people with asthma; approximately 80% of these patients are allergic to mold. Antimicrobial coatings are formulated to generate surfaces that are easy to clean and may also incorporate active agents, commonly called biocides, which inhibit microbial colonization, subsequent growth and bio-deterioration of the substrates. Some research lines seek to replace traditional organometallic and organochlorines biocides with environmentally acceptable ones. The aim of this research was, primarily, to explore the possible application of different compounds used in food industry like preservatives to be used as antimicrobial additives for antimicrobial coatings. Four biocides were tested against two different ambient molds isolated from an interior painted wall (Chaetomium globosum and Alternaria alternate). The selected biocides were zinc salicylate, zinc benzoate, calcium benzoate and potassium sorbate. The resulting paints were subjected to biological and physical tests (viscosity, hiding power, humidity absorption and biocides leaching rate). Bioassays revealed that zinc benzoate and zinc salicylate resulted active against both fungi.

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