Abstract. The Curiosity rover discovered fine--grained sedimentary rocks, inferred to represent an ancient lake, preserve evidence of an environment that would have been suited to support a Martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. C, H, O, S, N, and P were measured directly as key biogenic elements, and by inference N and P are assumed to have been available. The environment likely had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial--lacustrine environments in the post--Noachian history of Mars.

X-ray diffraction analysis of the Rocknest scoop sample is described in (23); similar analyses were performed for John Klein and Cumberland. John Klein and Cumberland were the first two drill samples collected by Curiosity. All scooped or drilled samples pass through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample collection and processing system (10). All powders for X-ray diffraction are processed through a 150-m sieve before delivering a portion to the CheMin inlet funnel.The sieved drill powders were placed into sample cells with 6 μm thick Mylar® windows. Mylar® contributes a minor, broad scattering signature in diffraction patterns that is generally "swamped" by diffraction from the loaded sample. In addition, an aluminized light shield also contributes "peaks" to the observed diffraction patterns. Only ~10 mm 3 of material is required to fill the active volume of the sample cell, which is a disc-shaped volume 8 mm in diameter and 175 m thick. A collimated ∼70 μm diameter X-ray beam illuminates the center of the sample cell. A piezoelectric vibration system on each cell pair shakes the material during analysis, causing grains in the cell to pass through the X-ray beam in random orientations.CheMin measures XRD and XRF data simultaneously using Co radiation in transmission geometry (11). The instrument operates in single-photon counting mode so that between each readout the majority of CCD pixels are struck by either a single X-ray photon or by no photons. In this way, the system can determine both the energy of the photons striking the CCD (XRF) and the two-dimensional (2-D) position of each photon (XRD). The energy and positional information of detected photons in each frame are summed over repeated 10-sec measurements into a "minor frame" of 30 min of data (180 frames). The 2-D distribution of Co K X-ray intensity represents the XRD pattern of the sample. Circumferential integration of these rings, corrected for arc length, produces a conventional 1-D XRD pattern. For conversion of the 2-D CCD pattern to a 1-D pattern we have used FilmScan © software from Materials Data, Inc.CheMin generally operates for only a few hours each night, when the CCD can be cooled to its lowest temperature, collecting as many minor frames as possible for the available analysis time, usually five to seven per night. XRD data were acquired over multiple nights for the John Klein and Cumberland drill samples to provide acceptable counting statistics. Total data collection times were 33.9 hr for John Klein and 20.2 hr for Cumberland. The data for individual minor frames and for each night's analysis were examined separately, and there was no evidence of any changes in instrumental parameters as a function of time over the duration of these analyses. Before sample delivery and analysis, the empty cell was analyzed to confirm that it was indeed empty before receiving the sample. The flight instrument was calibrated on the ground before flight using a quartz-beryl standard, and measurement of this st...

The Crystallography Open Database (COD), which is a project that aims to gather all available inorganic, metal-organic and small organic molecule structural data in one database, is described. The database adopts an openaccess model. The COD currently contains 80 000 entries in crystallographic information file format, with nearly full coverage of the International Union of Crystallography publications, and is growing in size and quality.

No abstract

Using an open-access distribution model, the Crystallography Open Database (COD, http://www.crystallography.net) collects all known ‘small molecule / small to medium sized unit cell’ crystal structures and makes them available freely on the Internet. As of today, the COD has aggregated ∼150 000 structures, offering basic search capabilities and the possibility to download the whole database, or parts thereof using a variety of standard open communication protocols. A newly developed website provides capabilities for all registered users to deposit published and so far unpublished structures as personal communications or pre-publication depositions. Such a setup enables extension of the COD database by many users simultaneously. This increases the possibilities for growth of the COD database, and is the first step towards establishing a world wide Internet-based collaborative platform dedicated to the collection and curation of structural knowledge.

The Mars Science Laboratory Curiosity rover has been traversing strata at the base of Aeolis Mons (informally known as Mount Sharp) since September 2014. The Murray formation makes up the lowest exposed strata of the Mount Sharp group and is composed primarily of finely laminated lacustrine mudstone intercalated with rare crossbedded sandstone that is prodeltaic or fluvial in origin. We report on the first three drilled samples from the Murray formation, measured in the Pahrump Hills section. Rietveld refinements and FULLPAT full pattern fitting analyses of X-ray diffraction patterns measured by the MSL CheMin instrument provide mineral abundances, refined unit-cell parameters for major phases giving crystal chemistry, and abundances of X-ray amorphous materials. Our results from the samples measured at the Pahrump Hills and previously published results on the Buckskin sample measured from the Marias Pass section stratigraphically above Pahrump Hills show stratigraphic variations in the mineralogy; phyllosilicates, hematite, jarosite, and pyroxene are most abundant at the base of the Pahrump Hills, and crystalline and amorphous silica and magnetite become prevalent higher in the succession. Some trace element abundances measured by APXS also show stratigraphic trends; Zn and Ni are highly enriched with respect to average Mars crust at the base of the Pahrump Hills (by 7.7 and 3.7 times, respectively), and gradually decrease in abundance in stratigraphically higher regions near Marias Pass, where they are depleted with respect to average Mars crust (by more than an order of magnitude in some targets). The Mn stratigraphic trend is analogous to Zn and Ni, however, Mn abundances are close to those of average Mars crust at the base of Pahrump Hills, rather than being enriched, and Mn becomes increasingly depleted moving upsection. Minerals at the base of the Pahrump Hills, in particular jarosite and hematite, as well as enrichments in Zn, Ni, and Mn, are products of acid-sulfate alteration on Earth. We hypothesize that multiple influxes of mildly to moderately acidic pore fluids resulted in diagenesis of the Murray formation and the observed mineralogical and geochemical variations. The preservation of some minerals that are highly susceptible to dissolution at low pH (e.g., mafic minerals and fluorapatite) suggests that acidic events were not long-lived and that fluids may not have been extremely acidic (pH>2). Alternatively, the observed mineralogical variations within the succession may be explained by deposition in lake waters with variable Eh and/or pH, where the lowermost sediments were deposited in an oxidizing, perhaps acidic lake setting, and sediments deposited in the upper Pahrump Hills and Marias Pass were deposited lake waters with lower Eh and higher pH

International audienceSamples from the Rocknest aeolian deposit were heated to ~835°C under helium flow and evolved gases analyzed by Curiosity's Sample Analysis at Mars instrument suite. H2O, SO2, CO2, and O2 were the major gases released. Water abundance (1.5 to 3 weight percent) and release temperature suggest that H2O is bound within an amorphous component of the sample. Decomposition of fine-grained Fe or Mg carbonate is the likely source of much of the evolved CO2. Evolved O2 is coincident with the release of Cl, suggesting that oxygen is produced from thermal decomposition of an oxychloride compound. Elevated δD values are consistent with recent atmospheric exchange. Carbon isotopes indicate multiple carbon sources in the fines. Several simple organic compounds were detected, but they are not definitively martian in origin

H 2 O, CO 2 , SO 2 , O 2 , H 2 , H 2 S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H 2 O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO 2 . Concurrent evolution of O 2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.