The mining industry generates a notable amount of mine tailings (MTs). Disposal of MTs creates environmental impacts such as air pollution and the release of heavy metals into surface and underground water. The European Union (EU)-funded project "Integrated mineral technologies for more sustainable raw material supply" (ITERAMS) includes an effort to produce eco-friendly backfill materials to enhance operation and mine safety and covers for surface deposits of tailings based on geopolymerization technology. This paper investigates the effects of activator concentration, curing temperature and time on alkali-activated materials based on low-alumina MTs from the Cu/Ni mine in Northern Finland. Alkaline activators containing sodium silicate solution (Na 2 SiO 3) at different concentrations were used and two different curing temperatures, 40 °C and 60 °C, for periods of 7, 14, and 28 days were considered. Scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDS) and X-ray diffraction (XRD) were performed to investigate the structure, morphology and phase compositions of the alkali-activated products. The effect of curing temperature and alkaline solutions on mechanical strength and water absorption were investigated. The results indicate that the alkalinity and curing temperature affect the mechanical and microstructural properties of the compositions of alkali-activated MTs. The 30 wt% Na 2 SiO 3 addition enables the alkali activated MT to improve the compressive strength with a highest value of 6.44 and 15.70 MPa after 28 days of curing at 40 °C and 60 °C, respectively. The results of this study deliver useful information for recycling and utilization of MTs as sustainable material through the alkali activation.
For ecologic and economic reasons tailings, waste rock and water management become progressively important factors in the mining industry. The European Union funded project ‘Integrated mineral technologies for more sustainable raw material supply’ (ITERAMS) aims to (1) close the water cycle of the mineral processing plant (i.e. minimizing the release of wastewater to the adjacent environment), and (2) to use tailings (and waste rock) as raw materials for geopolymers. This will (1) enable significantly more efficient water recycling at the mining sites, (2) deliver cost savings and added income due to the valorisation of solid waste residues, and (3) minimize the overall environmental footprint of the mining industry and will therefore help improving its performance and as a consequence its social position. The developed solutions influence the total lifecycle of the mining operation, as they provide input to project planning and operational phases as well as to the closure and recultivation. In this paper, the valorisation of the tailings and the waste rock is discussed. The main applications of the geopolymer products are (1) backfill material to fill open cavities from the mining operation and (2) a cover for surface deposits of tailings to store them environmentally safe – i.e. seal them off from surface water streams and oxidising conditions.
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