Both cryoporometry and relaxometry probe the surface-to-volume
ratio of a porous material. Nuclear magnetic resonance (NMR)
relaxometry uses the random motion of molecules, whereas
cryoporometry uses the melting-point depression of a confined
liquid. An NMR setup has been built to simultaneously perform
cryoporometry and relaxometry measurements. Using materials with
a well-defined pore size, i.e. silica gels, both methods
are compared with the standard N2-adsorption technique, and
a good correlation is found. The methods can be used in the pore
size range between 1 and 100 nm. By performing NMR relaxometry
during cryoporometry, more information about the pore-size
distribution can be obtained. Besides for silica gels, this is
demonstrated for mortar, which has a complicated pore structure.
. Random-walk simulations of NMR dephasing effects due to uniform magnetic-field gradients in a pore. Physical Review E, 65(2), 021306-1/8. DOI: 10.1103/PhysRevE.65.021306
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Take down policyIf you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. A random-walk simulation program was developed to study the effect of dephasing spins in a uniform magnetic-field gradient in a porous material. It is shown that this simulation program correctly reproduces basic nuclear magnetic resonance behavior, such as the formation of a spin echo. The spin-echo decay due to dephasing in a nonrestricted medium gives the well-known exponential relation containing the cube of time, whereas the spin-echo decay due to dephasing in a porous material gives a monoexponential decay. By varying the pore size and magnetic-field gradient, the motional averaging regime and the localization regime can be simulated. Moreover, the unknown intermediate regime is investigated. By choosing the right scaling parameters, the spin-echo decay due to dephasing in a pore can be described by one master curve for all pore sizes and gradient strengths. This master curve reveals a small intermediate regime, perfectly symmetrical around the gradient for which the dephasing length is exactly equal to the structural length of the pore.
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