Degeneracy of discrete energy levels of finite-length, metallic single-wall carbon nanotubes depends on type of nanotubes, boundary condition, length of nanotubes and spin-orbit interaction. Metal-1 nanotubes, in which two non-equivalent valleys in the Brillouin zone have different orbital angular momenta with respect to the tube axis, exhibits nearly fourfold degeneracy and small lift of the degeneracy by the spin-orbit interaction reflecting the decoupling of two valleys in the eigenfunctions. In metal-2 nanotubes, in which the two valleys have the same orbital angular momentum, vernierscale-like spectra appear for boundaries of orthogonal-shaped edge or cap-termination reflecting the strong valley coupling and the asymmetric velocities of the Dirac states. Lift of the fourfold degeneracy by parity splitting overcomes the spin-orbit interaction in shorter nanotubes with a socalled minimal boundary. Slowly decaying evanescent modes appear in the energy gap induced by the curvature of nanotube surface. Effective one-dimensional model reveals the role of boundary on the valley coupling in the eigenfunctions.

Semiconducting single-wall carbon nanotubes are classified into two types by means of orbital angular momentum of valley state, which is useful to study their low energy electronic properties in finite-length. The classification is given by an integer d, which is the greatest common divisor of two integers n and m specifying the chirality of nanotubes, by analyzing cutting lines. For the case that d is equal to or greater than four, two lowest subbands from two valleys have different angular momenta with respect to the nanotube axis. Reflecting the decoupling of two valleys, discrete energy levels in finite-length nanotubes exhibit nearly fourfold degeneracy and its small lift by the spin-orbit interaction. For the case that d is less than or equal to two, in which two lowest subbands from two valleys have the same angular momentum, discrete levels exhibit lift of fourfold degeneracy reflecting the coupling of two valleys. Especially, two valleys are strongly coupled when the chirality is close to the armchair chirality. An effective one-dimensional lattice model is derived by extracting states with relevant angular momentum, which reveals the valley coupling in the eigenstates. A bulk-edge correspondence, relationship between number of edge states and the winding number calculated in the corresponding bulk system, is analytically shown by using the argument principle, which enables us to estimate the number of edge states from the bulk property. The number of edge states depends not only on the chirality but also on the shape of boundary.

The Aharonov-Bohm effect in ring structures in the presence of electronic correlation and disorder is an open issue. We report novel oscillations of a strongly correlated exciton pair, similar to a Wigner molecule, in a single nanoquantum ring, where the emission energy changes abruptly at the transition magnetic field with a fractional oscillation period compared to that of the exciton, a so-called fractional optical Aharonov-Bohm oscillation. We have also observed modulated optical Aharonov-Bohm oscillations of an electron-hole pair and an anticrossing of the photoluminescence spectrum at the transition magnetic field, which are associated with disorder effects such as localization, built-in electric field, and impurities.

The topological phase transition is theoretically studied in a metallic single-wall carbon nanotube (SWNT) by applying a magnetic field $B$ parallel to the tube. The $\mathbb{Z}$ topological invariant, winding number, is changed discontinuously when a small band gap is closed at a critical value of $B$, which can be observed as a change in the number of edge states owing to the bulk-edge correspondence. This is confirmed by numerical calculations for finite SWNTs of $\sim$ 1 $\mu$m length, using a one-dimensional lattice model to effectively describe the mixing between $\sigma$ and $\pi$ orbitals and spin-orbit interaction, which are relevant to the formation of the band gap in metallic SWNTs.Comment: 8 pages, 4 figure

The single-wall carbon nanotube (SWNT) can be a one-dimensional topological insulator, which is characterized by a Z-topological invariant, winding number. Using the analytical expression for the winding number, we classify the topology for all possible chiralities of SWNTs in the absence and presence of a magnetic field, which belongs to the topological categories of BDI and AIII, respectively. We find that the majority of SWNTs are nontrivial topological insulators in the absence of a magnetic field. In addition, the topological phase transition takes place when the band gap is closed by applying a magnetic field along the tube axis, in all the SWNTs except armchair nanotubes. The winding number determines the number of edge states localized at the tube ends by the bulk-edge correspondence, the proof of which is given for SWNTs in general. This enables the identification of the topology in experiments.