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Cationic starch derivatives containing quaternary ammonium groups with high degree of substitution are prepared by reaction of starch with glycidyltrimethylammonium chloride (GTAC) in different reaction media. In aqueous solutions of GTAC along with conventional hydrolysis of epoxy groups, their interaction with chloride ions also takes place. This resulted in formation of hydroxyl ions which accelerate both the hydrolysis of GTAC epoxy groups and can act as the internal catalyst in the reaction of GTAC with starch. Therefore, even in the absence of the external catalyst, cationic starch with a high degree of substitution can be obtained. The autocatalytic reaction of GTAC with starch proceeds more rapidly at higher temperatures but with lower reaction efficiency. Both in the absence of the external catalyst and in the case when sodium alkali is used as a catalyst the reaction of starch with GTAC proceeds only when a particular quantity of “free” water is present in the system. When the NaOH as catalyst is used the reaction efficiency is about 90%. The yield of starch cationization reaction decreases when the quantity of “free” water is twice or thrice higher than required for starch modification to begin.

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