Many engineering applications, particularly in extreme environments, require components with properties that vary with location in the part. Functionally graded materials (FGMs), which possess gradients in properties such as hardness or density, are a potential solution to address these requirements. The laser-based additive manufacturing process of directed energy deposition (DED) can be used to fabricate metallic parts with a gradient in composition by adjusting the volume fraction of metallic powders delivered to the melt pool as a function of position. As this is a fusion process, secondary phases may develop in the gradient zone during solidification that can result in undesirable properties in the part. This work describes experimental and thermodynamic studies of a component built from 304L stainless steel © 2016. This manuscript version is made available under the Elsevier user license http://www.elsevier.com/open-access/userlicense/1.0/ incrementally graded to Inconel 625. The microstructure, chemistry, phase composition, and microhardness as a function of position were characterized by microscopy, energy dispersive spectroscopy, X-ray diffraction, and microindentation. Particles of secondary phases were found in small amounts within cracks in the gradient zone. These were ascertained to consist of transition metal carbides by experimental results and thermodynamic calculations. The study provides a combined experimental and thermodynamic computational modeling approach toward the fabrication and evaluation of a functionally graded material made by DED additive manufacturing.

Interest in additive manufacturing (AM) has dramatically expanded in the last several years, owing to the paradigm shift that the process provides over conventional manufacturing. Although the vast majority of recent work in AM has focused on three-dimensional printing in polymers, AM techniques for fabricating metal alloys have been available for more than a decade. Here, laser deposition (LD) is used to fabricate multifunctional metal alloys that have a strategically graded composition to alter their mechanical and physical properties. Using the technique in combination with rotational deposition enables fabrication of compositional gradients radially from the center of a sample. A roadmap for developing gradient alloys is presented that uses multi-component phase diagrams as maps for composition selection so as to avoid unwanted phases. Practical applications for the new technology are demonstrated in low-coefficient of thermal expansion radially graded metal inserts for carbon-fiber spacecraft panels.

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Over the 2010s technological improvements allowed metal additive manufacturing to graduate from a prototyping tool to a widespread, full-scale manufacturing process. Among the capabilities still under development, however, is the ability to locally tailor alloy composition and properties to fabricate bulk, complex geometry functionally graded materials (FGMs), eliminating the need for dissimilar-metal welds and joints. The challenge of compositional grading involves overcoming chemical, metallurgical, and thermal property differences to achieve a continuous structure between a wide range of selected combinations of alloys. In this review, examples are discussed of fabricating FGMs joining a variety of combinations of stainless, nickel, titanium and copper alloys, and FGMs joining metals to ceramics and metalmatrix composites. The change in design strategy enabled by practical FGMs may lead to effective use of biomimetic designs that are both much more efficient as well as aesthetically pleasing.