A sample of 413 soundings in close proximity to tornadic and nontornadic supercells is examined. The soundings were obtained from hourly analyses generated by the 40-km Rapid Update Cycle-2 (RUC-2) analysis and forecast system. A comparison of 149 observed soundings and collocated RUC-2 soundings in regional supercell environments reveals that the RUC-2 model analyses were reasonably accurate through much of the troposphere. The largest error tendencies were in temperatures and mixing ratios near the surface, primarily in 1-h forecast soundings immediately prior to the standard rawinsonde launches around 1200 and 0000 UTC. Overall, the RUC-2 analysis soundings appear to be a reasonable proxy for observed soundings in supercell environments. Thermodynamic and vertical wind shear parameters derived from RUC-2 proximity soundings are evaluated for the following supercell and storm subsets: significantly tornadic supercells (54 soundings), weakly tornadic supercells (144 soundings), nontornadic supercells (215 soundings), and discrete nonsupercell storms (75 soundings). Findings presented herein are then compared to results from previous and ongoing proximity soundings studies. Most significantly, proximity soundings presented here reinforce the findings of previous studies in that vertical shear and moisture within 1 km of the ground can discriminate between nontornadic supercells and supercells producing tornadoes with F2 or greater damage. Parameters that combine measures of buoyancy, vertical shear, and low-level moisture show the strongest ability to discriminate between supercell classes.

Blends and other multicomponent systems are used in various polymer applications to meet multiple requirements that cannot be fulfilled by a single material. In polymer optoelectronic devices it is often desirable to combine the semiconducting properties of the conjugated species with the excellent mechanical properties of certain commodity polymers. Here we investigate bicomponent blends comprising semicrystalline regioregular poly(3-hexylthiophene) and selected semicrystalline commodity polymers, and show that, owing to a highly favourable, crystallization-induced phase segregation of the two components, during which the semiconductor is predominantly expelled to the surfaces of cast films, we can obtain vertically stratified structures in a one-step process. Incorporating these as active layers in polymer field-effect transistors, we find that the concentration of the semiconductor can be reduced to values as low as 3 wt% without any degradation in device performance. This is in stark contrast to blends containing an amorphous insulating polymer, for which significant reduction in electrical performance was reported. Crystalline-crystalline/semiconducting-insulating multicomponent systems offer expanded flexibility for realizing high-performance semiconducting architectures at drastically reduced materials cost with improved mechanical properties and environmental stability, without the need to design all performance requirements into the active semiconducting polymer itself.

Radar-based convective modes were assigned to a sample of tornadoes and significant severe thunderstorms reported in the contiguous United States (CONUS) during 2003-11. The significant hail ($2-in. diameter), significant wind ($65-kt thunderstorm gusts), and tornadoes were filtered by the maximum event magnitude per hour on a 40-km Rapid Update Cycle model horizontal grid. The filtering process produced 22 901 tornado and significant severe thunderstorm events, representing 78.5% of all such reports in the CONUS during the sample period. The convective mode scheme presented herein begins with three radarbased storm categories: 1) discrete cells, 2) clusters of cells, and 3) quasi-linear convective systems (QLCSs). Volumetric radar data were examined for right-moving supercell (RM) and left-moving supercell characteristics within the three radar reflectivity designations. Additional categories included storms with marginal supercell characteristics and linear hybrids with a mix of supercell and QLCS structures. Smoothed kernel density estimates of events per decade revealed clear geographic and seasonal patterns of convective modes with tornadoes. Discrete and cluster RMs are the favored convective mode with southern Great Plains tornadoes during the spring, while the Deep South displayed the greatest variability in tornadic convective modes in the fall, winter, and spring. The Ohio Valley favored a higher frequency of QLCS tornadoes and a lower frequency of RM compared to the Deep South and the Great Plains. Tornadoes with nonsupercellular/non-QLCS storms were more common across Florida and the high plains in the summer. Significant hail events were dominated by Great Plains supercells, while variations in convective modes were largest for significant wind events.

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A sample of 22 901 tornado and significant severe thunderstorm events, filtered on an hourly 40-km grid, was collected for the period 2003-11 across the contiguous United States (CONUS). Convective mode was assigned to each case via manual examination of full volumetric radar data (Part I of this study), and environmental information accompanied each grid-hour event from the hourly objective analyses calculated and archived at the Storm Prediction Center (SPC). Sounding-derived parameters related to supercells and tornadoes formed the basis of this investigation owing to the dominance of right-moving supercells in tornado production and the availability of supercell-related convective parameters in the SPC environmental archive. The tornado and significant severe thunderstorm events were stratified by convective mode and season. Measures of buoyancy discriminated most strongly between supercell and quasi-linear convective system (QLCS) tornado events during the winter, while bulk wind differences and storm-relative helicity were similar for both supercell and QLCS tornado environments within in each season. The larger values of the effectivelayer supercell composite parameter (SCP) and the effective-layer significant tornado parameter (STP) favored right-moving supercells that produced significant tornadoes, as opposed to weak tornadoes or supercells that produced only significant hail or damaging winds. Additionally, mesocyclone strength tended to increase with increasing SCP for supercells, and STP tended to increase as tornado damage class ratings increased. The findings underscore the importance of convective mode (discrete or cluster supercells), mesocyclone strength, and near-storm environment (as represented by large values of STP) in consistent, realtime identification of intense tornadoes.

Blends of conjugated polymers are frequently used as the active semiconducting layer in light-emitting diodes and photovoltaic devices. Here we report the use of scanning near-field optical microscopy, scanning force microscopy and nuclear-reaction analysis to study the structure of a thin film of a phase-separated blend of two conjugated polymers prepared by spin-casting. We show that in addition to the well-known micrometre-scale phase-separated morphology of the blend, one of the polymers preferentially wets the surface and forms a 10-nm-thick, partially crystallized wetting layer. Using near-field microscopy we identify unexpected changes in the fluorescence emission from the blend that occurs in a 300-nm-wide band located at the interface between the different phase-separated domains. Our measurements provide an insight into the complex structure of phase-separated conjugated-polymer thin films. Characterizing and controlling the properties of the interfaces in such films will be critical in the further development of efficient optoelectronic devices.

[1] The Radiation Transfer Model Intercomparison (RAMI) initiative benchmarks canopy reflectance models under well-controlled experimental conditions. Launched for the first time in 1999, this triennial community exercise encourages the systematic evaluation of canopy reflectance models on a voluntary basis. The first phase of RAMI focused on documenting the spread among radiative transfer (RT) simulations over a small set of primarily 1-D canopies. The second phase expanded the scope to include structurally complex 3-D plant architectures with and without background topography. Here sometimes significant discrepancies were noted which effectively prevented the definition of a reliable ''surrogate truth,'' over heterogeneous vegetation canopies, against which other RT models could then be compared. The present paper documents the outcome of the third phase of RAMI, highlighting both the significant progress that has been made in terms of model agreement since RAMI-2 and the capability of/need for RT models to accurately reproduce local estimates of radiative quantities under conditions that are reminiscent of in situ measurements. Our assessment of the self-consistency and the relative and absolute performance of 3-D Monte Carlo models in RAMI-3 supports their usage in the generation of a ''surrogate truth'' for all RAMI test cases. This development then leads (1) to the presentation of the ''RAMI Online Model Checker'' (ROMC), an open-access web-based interface to evaluate RT models automatically, and (2) to a reassessment of the role, scope, and opportunities of the RAMI project in the future.

The phase behavior, adsorption, and aggregation of semifluorinated alkanes (SFAs) of general structure F(CF2)n(CH2)mH (abbreviated to FnHm) in hydrocarbon and fluorocarbon solvents has been investigated. The SFAs form a novel class of structurally primitive surfactants, and their behavior in mixtures with hydrocarbon and fluorocarbon solvents is compared with that of conventional surfactants in mixtures with oil and water. Miscibility studies of hydrocarbon and fluorocarbon solvents of different chain lengths show that the free energies of transfer of -CH 2-from hydrocarbon to fluorocarbon phases and -CF2-from fluorocarbon to hydrocarbon are 1.1 and 1.4 kJ mol -1 respectively. These values are approximately onethird of the free energy of transfer of a -CH2-group from alkane to water. Hence, SFAs are expected to be only weakly amphiphilic when compared with conventional surfactants of similar chain lengths in oil + water systems. This expectation is confirmed by SFA solubility and aggregation measurements which show that SFAs aggregate weakly in both hydrocarbon and fluorocarbon solvents to give aggregates with aggregation numbers in the range 2-10. SFAs adsorb at the hydrocarbon-air and hydrocarbonfluorocarbon interfaces but not at the fluorocarbon-air surface. A limited number of two-phase ternary mixtures of SFA with hydrocarbon and fluorocarbon solvents were studied. No evidence for the formation of "middle phase" microemulsions was observed, again consistent with the relatively weak amphiphilicity of SFAs.