This article reviews mentoring literature and presents the findings emerging from research into the dynamics of mentoring and how similarities and differences between mentor and mentee influence learning for both parties and the organisation. The principal organisations contributing to the research, Scottish Hydro‐Electric and Skipton Building Society, used different approaches to matching mentor and mentee. Theoretical models are developed from the findings that suggest that similarity will support the development of rapport whereas contrasts support learning. However, the importance of personal values should not be ignored.
As the location and accessibility of hydrocarbons is key to understanding and improving the extractability of hydrocarbons in hydraulic fracturing, this study is an attempt to understand how native organics are distributed with respect to pore size to determine the relationship between hydrocarbon chemistry and pore structure in shales.First, selected shale cores from the Eagle Ford and Marcellus formations were subjected to pyrolysis gas chromatography (GC),thermogravimetric analysis, and organic solvent extraction with the resulting effluent analyzed by GC-mass spectrometry (MS). Organics representing the oil and gas fraction (0.1 to 1 wt. %) were observed by GC-MS. For most of the samples, the amount of native organic extracted directly related to the percentage of clay in the shale. The porosity and pore size distribution (0.95 nm to 1.35µm)in the Eagle Ford and Marcellus shales was measured before and after solvent extraction using small angle neutron scattering (SANS). An unconventional method was used to quantify the background from incoherent scattering as the Porod transformation obscures the Bragg peak from the clay minerals. The change in porosity from SANS is indicative of the extraction or breakdown of higher molecular weight bitumen with high
Hydraulic fracturing of gas shale formations involves pumping a large volume of fracking fluid into a hydrocarbon reservoir to fracture the rock and thus increase its permeability.The majority of the fracking fluid introduced is never recovered and the fate of this lost fluid, often called "leak off," has become the source of much debate. Information on the capillary pressuresaturation relationship for each wetting phase is needed to simulate leak off using numerical reservoir models. The petroleum industry commonly employs airwater capillary pressuresaturation curves to predict these relationships for mixed wet reservoirs. Traditional methods of measuring this curve are unsuitable for gas shale's due to high capillary pressures associated with the small pores present. A possible alternative method is the water activity meter which is used widely in the soil sciences for such measurements. However, its application to lithified material has been limited. This study utilized a water activity meter to measure airwater capillary pressures (ranging from 1.3 -219.6 MPa) at several water saturation levels in both the wetting and drying directions. Water contents were measured gravimetrically. Seven types of gas producing shale with different porosities (2.5 -13.6%) and total organic carbon contents (0.4 -13.5%) were investigated. Nonlinear regression was used to fit the resulting capillary pressurewater saturation data pairs for each shale type to the Brooks and Corey equation. Data for six of the seven shale types investigated were successfully fitted (median R 2 = 0.93), indicating this may be a viable method for parameterizing capillary pressuresaturation relationships for inclusion in numerical reservoir models. As expected, the different shale types had statistically different Brooks and Corey parameters. However, there were no significant differences between the Brooks and Corey parameters for the wetting and drying measurements, suggesting that hysteresis may not need to be taken into account in leak off simulations.
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