Two-dimensional supramolecular clusters and chains are observed upon submonolayer deposition of 1-nitronaphthalene (NN) onto reconstructed Au(111). The molecules become pseudochiral upon adsorption. Their handedness is determined from high-resolution scanning tunneling microscope images and local-density calculations. Modeling shows that hydrogen bonds cause the observed self-assembly. Clusters and chains mutually interact via electrostatic repulsion
In this Communication, the preparation conditions of the molecular films were described incorrectly. During the deposition of [Fe(bpz) 2 phen], the Au(111) substrate temperature was kept at about 100 8C. This correction does not affect the conclusions of the original Communication.
A long-standing discrepancy between experimental and theoretical values for the lifetimes of holes in the surface-state electron bands on noble metal surfaces is resolved; previous determinations of both are found to have been in error. The ability of the scanning tunneling microscope to verify surface quality before taking spectroscopic measurements is used to remove the effects of defect scattering on experimental lifetimes, found to have been a significant contribution to prior determinations. A theoretical treatment of inelastic electron-electron scattering is developed that explicitly includes intraband transitions within the surface state band. In our model, two-dimensional decay channels dominate the electron-electron interactions that contribute to the hole decay and are screened by the electron states of the underlying three-dimensional electron system.
Molecule-based functional devices on surfaces may take advantage of bistable molecular switches. The conformational dynamics and efficiency of switches are radically different on surfaces compared to the liquid phase. We present a design of molecular layers which enables bistable switching on a surface and, for the first time, demonstrate control of a single switch in a dense and ordered array at the spatial limit. Up and down motion of a central Sn ion through the frame of a phthalocyanine molecule is achieved via resonant electron or hole injection into molecular orbitals.
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