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Analytical studies of placer (detrital) gold grains, intended to track bedrock sources and styles of mineralization, mainly consider alloy Ag content and inclusion mineralogy to generate 'microchemical signatures'. Occasionally Hg and Pd help discriminate gold from different sources; Cu infrequently because electron microprobes seldom detect the low concentrations. Reporting of Cu has been largely confined to gold from porphyry-epithermal environments, and this has biased subsequent interpretations of observed Cu-bearing gold alloys.This study focuses on placer gold in the Mourne Mountains, Northern Ireland, where auriferous bedrock remains undiscovered and the complex geology is consistent with either orogenic or intrusion-related mineralization. Over 500 gold grains analysed average 0.17% Cu ranging to >1% Cu and show a wide variation in Ag content. Inclusion mineralogy mainly matches that of orogenic gold elsewhere in the host terrane; however, some signatures are suggestive of zonation within an orogenic hydrothermal mineralizing system, or possibly metamorphic-hydrothermal remobilized gold associated with subsequent intrusive activity. One locality in the study area has placer gold of a distinctive Cu-rich alloy composition containing Cu sulphide inclusions, an association noted elsewhere in gold derived from alkali Cu-Au porphyries.Consideration of Cu-bearing gold alloys worldwide indicates that previously proposed compositional correlations with deposit type are of limited value. We show that Cu contents to at least 0.8% are permissible within orogenic gold -the first time that such compositions have been clearly ascribed to orogenic mineralization. The result is particularly important considering on-going exploration in northern Canada which employs gold grain analysis to help define exploration targets.

Phosphorus significantly influences the eutrophication process, modifying the quality of waterways and habitat, especially in stagnant waterbodies exposed to septic tank effluent at high nutrient levels. This research explores the development of a cost-effective, efficient, and affordable on-site wastewater treatment system targeted as total phosphorus (TP) removal technology. The research objective is to demonstrate the TP removal efficiency of an optimized clay-zeolite medium by chemical adsorption. The study observes the effects of pellet medium design and modifications, influent concentrations, and contact time. Following various stages of optimization, the preliminary testing achieves a 45 ± 1.8% removal after 45 minutes of contact time. The optimized pellets are contained within a five-layer bench-scale model, achieving equilibrium TP removal of 72 ± 2.9% after 3 hours. Theoretical extrapolation to 12 contact hours indicates an achievement of 88% removal is possible. The results show a positive correlation with the linearized Langmuir and Freundlich adsorption isotherms.

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