Richard A. Kretchmer scite author profile

The reaction of 2-cyclohexenone, 3-penten-2-one, and 1,3-dipheny 1-2-propen-1 -one with a series of Grignard reagents has been studied in the presence of (-)-sparteine (4) and other additives. The resulting conjugate addition products possess an optical purity of 3-6% and represent the first examples of asymmetric 1,4 addition of achiral organometallic reagents to pro chiral ,ß-unsaturated ketones. Subsequent reactions of enolate anions

show abstract

Organomercury compounds as synthetic intermediates. Coupling of arylmercuric salts

Kretchmer¹,

Glowinski²

1976

J. Org. Chem.

View full text Add to dashboard Cite

Reaction of benzalacetophenone with methylmagnesium iodide. Novel Grignard reaction

Kretchmer¹

1972

J. Org. Chem.

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.