The long-term mechanical stability of the gasket material is critical to sealing and electrochemical performance of the polymer electrolyte membrane (PEM) fuel cells. In this paper, the silicone rubber material, which is being considered as gasket material for PEM fuel cells, was fabricated at different curing temperatures and different curing pressures. Effects of the curing temperatures and curing pressures on the mechanical properties of the silicone rubber material were investigated. The tensile test results show that tensile strength of the specimen cured at the curing temperature of 160 was larger than that for the specimens cured at the curing temperature of 150 or 170 under the same curing pressure. The test results of the compression stress-strain, compression set and compression stress relaxation show that the curing temperature and curing pressure affected significantly the compression elastic modulus, compression set rate and compression stress relaxation behavior. It is found that the silicone rubber material cured at the curing temperature of 160 under the curing pressure of 10MPa had good compression mechanical properties compared to the materials cured at the other curing temperatures and curing pressure in this work.
Shift reactors are widely used in the petroleum and chemical industries, and especially in the coal chemical plants. The degradation of the reactor is critical to the safe operation of coal chemical plant. In this paper, a shift reactor after 8 year service was chosen. The test block taken from the reactor cylinder with the stainless steel clad plate was used and the test samples from the test block were prepared. And then, chemical composition analysis, metallographic examination, tensile and hardness tests were performed. The scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) method were used to study the degradation and degradation mechanism of the reactor. The metallographic analysis results show that there were a large number of carbides segregated in the grain boundary and the intergranular cracks were observed for the samples in the weld zone of the stainless steel clad plate. The SEM and EDS results indicate that the corrosion medium (i.e. polythionic acid) was found in the fracture surface of the samples from the weld zone of the stainless steel clad plate. The XRD test results show that the tensile residual stress occurred for the welding of the stainless steel clad plates. It is found that the degradation mechanism of the shift reactor was due to the polythionic acid stress corrosion cracking.
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