The principal inhibitor of fast charging lithium ion cells is the graphite negative electrode, where favorable conditions for lithium plating occur at high charge rates, causing accelerated degradation and safety...
The next generation of automotive lithium‐ion batteries may employ NMC811 materials; however, defective particles are of significant interest due to their links to performance loss. Here, it is demonstrated that even before operation, on average, one‐third of NMC811 particles experience some form of defect, increasing in severity near the separator interface. It is determined that defective particles can be detected and quantified using low resolution imaging, presenting a significant improvement for material statistics. Fluorescence and diffraction data reveal that the variation of Mn content within the NMC particles may correlate to crystallographic disordering, indicating that the mobility and dissolution of Mn may be a key aspect of degradation during initial cycling. This, however, does not appear to correlate with the severity of particle cracking, which when analyzed at high spatial resolutions, reveals cracking structures similar to lower Ni content NMC, suggesting that the disconnection and separation of neighboring primary particles may be due to electrochemical expansion/contraction, exacerbated by other factors such as grain orientation that are inherent in such polycrystalline materials. These findings can guide research directions toward mitigating degradation at each respective length‐scale: electrode sheets, secondary and primary particles, and individual crystals, ultimately leading to improved automotive ranges and lifetimes.
a Lithium-ion batteries are being used in increasingly demanding applications where safety and reliability are of utmost importance. Thermal runaway presents the greatest safety hazard, and needs to be fully understood in order to progress towards safer cell and battery designs. Here, we demonstrate the application of an internal short circuiting device for controlled, on-demand, initiation of thermal runaway. Through its use, the location and timing of thermal runaway initiation is pre-determined, allowing analysis of the nucleation and propagation of failure within 18 650 cells through the use of high-speed X-ray imaging at 2000 frames per second. The cause of unfavourable occurrences such as sidewall rupture, cell bursting, and cell-to-cell propagation within modules is elucidated, and steps towards improved safety of 18 650 cells and batteries are discussed. Broader contextFrom portable electronics to grid-scale storage, high energy density Li-ion batteries are ubiquitous in today's society. Such cells can and do fail, sometimes catastrophically, releasing large amounts of energy. To facilitate safer and more reliable cell designs, the importance of understanding failure mechanisms of Li-ion cells is widely recognised. Here, we demonstrate the application of a novel device that is capable of generating an internal short circuit within commercial cell designs, on-demand, and at a predetermined location. This enables us to test more effectively the ability of safety devices of cells and modules to withstand 'worst-case' failure scenarios. By combining the use of this device with high-speed X-ray imaging at 2000 frames per second, we characterise for the first time the initiation and propagation of thermal runaway from a known location within a Li-ion cell. The insights achieved in this study are expected to guide the design and development of safer and more reliable Li-ion cells.
a required reduction in emissions per unit production of 75% by 2050 in order to have a 50% chance of limiting global mean temperature rise by 2 °C compared to pre-industrial levels. [1,2] Improvements in the field of electrocatalysts, especially in relation to electrolyzers and fuel cells, will help these devices become part of the solution to the looming sustainable energy and chemical production needs. [3] For these devices to be entirely renewable, H 2 (and O 2 ) needs to be produced by water splitting in electrolyzers through H 2 and O 2 evolution (green hydrogen production), rather than from methane reforming (grey hydrogen production). [4,5] H 2 can then be used in electrochemical O 2 reduction in fuel cells to produce electricity. [6,7] Meanwhile, electrochemical reduction of N 2 to NH 3 can provide a sustainable means to a critical fertilization source for the agricultural industry and a carrier for H 2 . [8] Moreover, a way of producing value-added products and a "circular economy" for industry from CO 2 emissions is via the electrocatalytically driven CO 2 reduction, which converts CO 2 to essential feedstocks, such as ethylene or ethanol for the chemical industry. [9] Low-temperature fuel cells and electrolyzers typically utilize catalysts based on platinum group metal (PGM) nanoparticles, [10] which limits device commercialization due to increasing global demand, low uptake of recycling, and high cost of PGMs. [11] Consequently, many researchers have turned their attention to reducing PGM loading or entirely replacing them with lower-cost earth-abundant metals, such as Fe, Cu, Ni, Co, Mn, and, most recently, Sn. [12] Regardless of the catalyst composition, improvements in the electrochemical activity have been highly sought after with two general options available; increasing the number of accessible catalytic sites and/or increasing the intrinsic activity of the catalytic sites. [13] Many different catalyst designs have been explored in order to raise the activity, such as alloying [14] or nanostructuring. [15] While increasing the density of catalytic sites improves activity, this method becomes physically limited when catalyst loading affects charge and mass transport. [13] Thus, improving the activity per catalytic site (intrinsic activity) through controlling local geometry and electronic structure has garnered research attention, with successful methods including shrinking the catalytic site down to atomic scale, as well as locally introducing light heteroatoms or hosting the catalytic site at edges. [10,[16][17][18] Electrochemical clean energy conversion and the production of sustainable chemicals are critical in the journey to realizing a truly sustainable society. To progress electrochemical storage and conversion devices to commercialization, improving the electrocatalyst performance and cost are of utmost importance. Research into dual-metal atom catalysts (DACs) is rising in prominence due to the advantages of these sites over single-metal atom catalysts (SACs), such as breaking scaling ...
Batteries that extend performance beyond the intrinsic limits of Li-ion batteries are among the most important developments required to continue the revolution promised by electrochemical devices. Of these next-generation batteries, lithium sulfur (Li–S) chemistry is among the most commercially mature, with cells offering a substantial increase in gravimetric energy density, reduced costs and improved safety prospects. However, there remain outstanding issues to advance the commercial prospects of the technology and benefit from the economies of scale felt by Li-ion cells, including improving both the rate performance and longevity of cells. To address these challenges, the Faraday Institution, the UK’s independent institute for electrochemical energy storage science and technology, launched the Lithium Sulfur Technology Accelerator (LiSTAR) programme in October 2019. This Roadmap, authored by researchers and partners of the LiSTAR programme, is intended to highlight the outstanding issues that must be addressed and provide an insight into the pathways towards solving them adopted by the LiSTAR consortium. In compiling this Roadmap we hope to aid the development of the wider Li–S research community, providing a guide for academia, industry, government and funding agencies in this important and rapidly developing research space.
Sustainable energy production at an acceptable cost is key for its widespread application. At present, noble metals and metal oxides are the most widely used for electrocatalysis, but they suffer from low selectivity, poor durability, and scarcity. Because of this, metal‐free carbons have become the subject of great interest as promising alternative electrocatalysts for energy conversion and storage devices, and remarkable progress has been accomplished in the advance of metal‐free carbons as electrocatalysts for renewable energy technologies. Particularly interesting are 3D porous carbon architectures, which exhibit outstanding features for electrocatalysis applications, including broad range of active sites, interconnected porosity, high conductivity, and mechanical stability. This review summarizes the latest advances in 3D porous carbon structures for oxygen and hydrogen electrocatalysis. The structure–performance relationship of these materials is consequently rationalized and perspectives on creating more efficient 3D carbon electrocatalysts are suggested.
Understanding and ultimately controlling the properties of the solid–electrolyte interphase (SEI) layer at the graphite anode/liquid electrolyte boundary are of great significance for maximizing the performance and lifetime of lithium-ion batteries (LIBs). However, comprehensive in situ monitoring of SEI formation and evolution, alongside measurement of the corresponding mechanical properties, is challenging due to the limitations of the characterization techniques commonly used. This work provides a new insight into SEI formation during the first lithiation and delithiation of graphite battery anodes using operando electrochemical atomic force microscopy (EC-AFM). Highly oriented pyrolytic graphite (HOPG) is investigated first as a model system, exhibiting unique morphological and nanomechanical behavior dependent on the various electrolytes and commercially relevant additives used. Then, to validate these findings with respect to real-world battery electrodes, operando EC-AFM of individual graphite particles like those in commercial systems are studied. Vinylene carbonate (VC) and fluoroethylene carbonate (FEC) are shown to be effective additives to enhance SEI layer stability in 1 M LiPF 6 /ethylene carbonate/ethyl methyl carbonate (EC/EMC) electrolytes, attributed to their role in improving its structure, density, and mechanical strength. This work therefore presents an unambiguous picture of SEI formation in a real battery environment, contributes a comprehensive insight into SEI formation of electrode materials, and provides a visible understanding of the influence of electrolyte additives on SEI formation.
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