Despite the outstanding role of mesoscopic structures on the efficiency and stability of perovskite solar cells (PSCs) in the regular (n–i–p) architecture, mesoscopic PSCs in inverted (p–i–n) architecture have rarely been reported. Herein, an efficient and stable mesoscopic NiOx (mp‐NiOx) scaffold formed via a simple and low‐cost triblock copolymer template‐assisted strategy is employed, and this mp‐NiOx film is utilized as a hole transport layer (HTL) in PSCs, for the first time. Promisingly, this approach allows the fabrication of homogenous, crack‐free, and robust 150 nm thick mp‐NiOx HTLs through a facile chemical approach. Such a high‐quality templated mp‐NiOx structure promotes the growth of the perovskite film yielding better surface coverage and enlarged grains. These desired structural and morphological features effectively translate into improved charge extraction, accelerated charge transportation, and suppressed trap‐assisted recombination. Ultimately, a considerable efficiency of 20.2% is achieved with negligible hysteresis which is among the highest efficiencies for mp‐NiOx based inverted PSCs so far. Moreover, mesoscopic devices indicate higher long‐term stability under ambient conditions compared to planar devices. Overall, these results may set new benchmarks in terms of performance for mesoscopic inverted PSCs employing templated mp‐NiOx films as highly efficient, stable, and easy fabricated HTLs.

Ordered and disordered mesoporous titania thick films up to about 7 µm in thickness were successfully synthesized by an evaporation-induced self-assembly (EISA) process using dip and spin coating methods. To obtain crack-free thick films with high crystallinity and roughness factor we used a stabilization step after each coating and a calcination step after each five layers. Transmission electron microscopy (TEM), 10 X-ray diffraction (XRD), scanning electron microscopy (SEM), BET analysis, ellipsometric analysis and UV-visible absorption spectroscopy (UV-vis) were used to characterize the microstructural features of the films. These mesoporous TiO 2 thick films were tested in dye-sensitized solar cells (DSSCs). The photovoltaic performances of cells made from meso-films prepared by dip and spin coating methods were compared and a maximum efficiency of 8.33% was achieved. This is the highest efficiency so far 15 reported for DSSCs made from mesoporous titania templated films. The mesostructured films were compared with nanocrystalline TiO 2 films (NC-TiO 2 ) that are commonly used in DSSCs and showed superior performance.

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Hydraulic fracturing of a naturally fractured reservoir is a challenge for petroleum industry, as fractures can have complex growth patterns when propagating in systems of natural fractures that leads to significant diversion of hydraulic fracture paths due to intersection with natural fractures which causes difficulties in proppant transport. In this study, an eXtended Finite Element Method (XFEM) model has been developed to account for hydraulic fracture propagation and interaction with natural fracture in naturally fractured reservoirs including fractures intersection criteria into the model. It is assumed that fractures are propagating in an elastic medium under plane strain and quasi-static conditions. The results indicate that hydraulic fracture diversion before and after intersecting with natural fracture is strongly controlled by the in-situ horizontal differential stress and the orientation of the natural fractures as well as hydraulic fracture net pressure. It is observed that hydraulic fracture net pressure increase leads to decreasing induced fracture diversion and in-situ horizontal differential stress decrease results in increasing induced fracture diversion before intersecting with natural fracture. In addition, potential debonding of sealed natural fracture in the near-tip region of a propagating hydraulic fracture before fractures intersection has been modeled which is one of the phenomena that has been rarely taken into account, as debonding of natural fracture before fractures intersection is of great importance that may lead to diverting the induced fracture into double-deflection in natural fracture and can explain hydraulic fracture behaviors due to interaction with natural fracture at different conditions. Also, it’s been observed that at low angles of approach with low to high differential stress, the induced hydraulic fracture opens the natural fracture while at high to medium angles of approach, natural fracture opening and crossing both are observed depending on the differential stress. Comparison of the numerical and experimental studies results has shown good agreement.