A new version of the Fast Airglow Imager (FAIM) for the detection of atmospheric waves in the OH airglow layer has been set up at the German Remote Sensing Data Center (DFD) of the German Aerospace Center (DLR) at Oberpfaffenhofen (48.09 • N, 11.28 • E), Germany. The spatial resolution of the instrument is 17 m pixel −1 in zenith direction with a field of view (FOV) of 11.1 km × 9.0 km at the OH layer height of ca. 87 km. Since November 2015, the system has been in operation in two different setups (zenith angles 46 and 0 • ) with a temporal resolution of 2.5 to 2.8 s.In a first case study we present observations of two small wave-like features that might be attributed to gravity wave instabilities. In order to spectrally analyse harmonic structures even on small spatial scales down to 550 m horizontal wavelength, we made use of the maximum entropy method (MEM) since this method exhibits an excellent wavelength resolution. MEM further allows analysing relatively short data series, which considerably helps to reduce problems such as stationarity of the underlying data series from a statistical point of view. We present an observation of the subsequent decay of well-organized wave fronts into eddies, which we tentatively interpret in terms of an indication for the onset of turbulence.Another remarkable event which demonstrates the technical capabilities of the instrument was observed during the night of 4-5 April 2016. It reveals the disintegration of a rather homogenous brightness variation into several filaments moving in different directions and with different speeds. It resembles the formation of a vortex with a horizontal axis of rotation likely related to a vertical wind shear. This case shows a notable similarity to what is expected from theoretical modelling of Kelvin-Helmholtz instabilities (KHIs).The comparatively high spatial resolution of the presented new version of the FAIM provides new insights into the structure of atmospheric wave instability and turbulent processes. Infrared imaging of wave dynamics on the subkilometre scale in the airglow layer supports the findings of theoretical simulations and modellings.

Abstract. Between December 2013 and August 2017 the instrument FAIM (Fast Airglow IMager) observed the OH airglow emission at two Alpine stations. A year of measurements was performed at Oberpfaffenhofen, Germany (48.09∘ N, 11.28∘ E) and 2 years at Sonnblick, Austria (47.05∘ N, 12.96∘ E). Both stations are part of the network for the detection of mesospheric change (NDMC). The temporal resolution is two frames per second and the field-of-view is 55 km × 60 km and 75 km × 90 km at the OH layer altitude of 87 km with a spatial resolution of 200 and 280 m per pixel, respectively. This resulted in two dense data sets allowing precise derivation of horizontal gravity wave parameters. The analysis is based on a two-dimensional fast Fourier transform with fully automatic peak extraction. By combining the information of consecutive images, time-dependent parameters such as the horizontal phase speed are extracted. The instrument is mainly sensitive to high-frequency small- and medium-scale gravity waves. A clear seasonal dependency concerning the meridional propagation direction is found for these waves in summer in the direction to the summer pole. The zonal direction of propagation is eastwards in summer and westwards in winter. Investigations of the data set revealed an intra-diurnal variability, which may be related to tides. The observed horizontal phase speed and the number of wave events per observation hour are higher in summer than in winter.

Abstract. The period range between 6 and 480 min is known to represent the major part of the gravity wave spectrum driving mesospheric dynamics. We present a method using wavelet analysis to calculate gravity wave activity with a high period resolution and apply it to temperature data acquired with the OH* airglow spectrometers called GRIPS (GRound-based Infrared P-branch Spectrometer) within the framework of the NDMC (Network for the Detection of Mesospheric Change; https://ndmc.dlr.de, last access: 22 September 2020). We analyse data measured at the NDMC sites Abastumani in Georgia (ABA; 41.75∘ N, 42.82∘ E), ALOMAR (Arctic Lidar Observatory for Middle Atmosphere Research) in Norway (ALR; 69.28∘ N, 16.01∘ E), Neumayer Station III in the Antarctic (NEU; 70.67∘ S, 8.27∘ W), Observatoire de Haute-Provence in France (OHP; 43.93∘ N, 5.71∘ E), Oberpfaffenhofen in Germany (OPN; 48.09∘ N, 11.28∘ E), Sonnblick in Austria (SBO; 47.05∘ N, 12.95∘ E), Tel Aviv in Israel (TAV; 32.11∘ N, 34.80∘ E), and the Environmental Research Station Schneefernerhaus on top of Zugspitze mountain in Germany (UFS; 47.42∘ N, 10.98∘ E). All eight instruments are identical in construction and deliver consistent and comparable data sets. For periods shorter than 60 min, gravity wave activity is found to be relatively low and hardly shows any seasonal variability on the timescale of months. We find a semi-annual cycle with maxima during winter and summer for gravity waves with periods longer than 60 min, which gradually develops into an annual cycle with a winter maximum for longer periods. The transition from a semi-annual pattern to a primarily annual pattern starts around a gravity wave period of 200 min. Although there are indications of enhanced gravity wave sources above mountainous terrain, the overall pattern of gravity wave activity does not differ significantly for the abovementioned observation sites. Thus, large-scale mechanisms such as stratospheric wind filtering seem to dominate the evolution of mesospheric gravity wave activity.

Small semiconductor nanoclusters exhibit unique properties often very different from those of their atomic and bulk counterparts. Their better understanding and characterization is expected to be useful in the development of highly functional cluster-assembled materials (CAMs) with tunable properties. In this work, the structural and electronic properties of size-selected (CdO) n – clusters were examined by conventional and time-resolved spectroscopy (TR-PES) combined with density functional theory (DFT) calculations. The observed highly symmetric alternant-cage structures and large band gaps confirm the validity of those species as CAM building blocks. Moreover, our results demonstrate a striking similarity between (CdO) n – and (ZnO) n – clusters of the same size that is not restricted to the ground state but also comprises properties of excited states. We suggest that in general valence isoelectronic small binary (XY) n clusters might exhibit similar structures and comparable properties. The long lifetimes of excited states observed in our experiment are proposed as a general probe helpful in identifying suitable structures for CAMs and hence simplifying their design.

Abstract. We analysed 286 nights of data from the OH* airglow imager FAIM 3 (Fast Airglow IMager) acquired at Otlica Observatory (45.93∘ N, 13.91∘ E), Slovenia, between 26 October 2017 and 6 June 2019. Measurements have been performed with a spatial resolution of 24 m per pixel and a temporal resolution of 2.8 s. A two-dimensional fast Fourier transform is applied to the image data to derive horizontal wavelengths between 48 m and 4.5 km in the upper mesosphere/lower thermosphere (UMLT) region. In contrast to the statistics of larger-scale gravity waves (horizontal wavelength up to ca. 50 km; Hannawald et al., 2019), we find a more isotropic distribution of directions of propagation, pointing to the presence of wave structures created above the stratospheric wind fields. A weak seasonal tendency of a majority of waves propagating eastward during winter may be due to instability features from breaking secondary gravity waves that were created in the stratosphere. We also observe an increased southward propagation during summer, which we interpret as an enhanced contribution of secondary gravity waves created as a consequence of primary wave filtering by the meridional mesospheric circulation. We present multiple observations of turbulence episodes captured by our high-resolution airglow imager and estimated the energy dissipation rate in the UMLT from image sequences in 25 cases. Values range around 0.08 and 9.03 W kg−1 and are on average higher than those in recent literature. The values found here would lead to an approximated localized maximum heating of 0.03–3.02 K per turbulence event. These are in the same range as the daily chemical heating rates for the entire atmosphere reported by Marsh (2011), which apparently stresses the importance of dynamical energy conversion in the UMLT.

Abstract. We analysed 286 nights of data from the OH* airglow imager FAIM 3 (Fast Airglow IMager) acquired at Otlica Observatory (45.93 °N, 13.91 °E), Slovenia between 26 October 2017 and 6 June 2019. Measurements have been performed with a spatial resolution of 24 m/pixel and a temporal resolution of 2.8 s. A two-dimensional Fast Fourier transform is applied to the image data to derive horizontal wavelengths between 48 m and 4.5 km in the upper mesosphere / lower thermosphere (UMLT) region. In contrast to the statistics of larger scale gravity waves (horizontal wavelength up to ca. 50 km) we find a more isotropic distribution of directions of propagation, pointing to the presence of wave structures created above the stratospheric wind fields. A weak seasonal tendency of a majority of waves propagating eastward (westward) during winter (summer) may be due to secondary gravity waves originating from breaking primary waves in the stratosphere. We also observe an increased southward propagation during summer, which we interpret as an enhanced contribution of secondary gravity waves created as a consequence of primary wave filtering by the meridional mesospheric circulation. Furthermore, observations of turbulent vortices allowed the estimation of eddy diffusion coefficients in the UMLT from image sequences in 45 cases. Values range around 103–104 m2s-1 and mostly agree with literature. Turbulently dissipated energy is derived taking into account values of the Brunt-Väisälä frequency based on TIMED-SABER (Thermosphere Ionosphere Mesosphere Energetics Dynamics, Sounding of the Atmosphere using Broadband Emission Radiometry) measurements. Energy dissipation rates range between 0.63 W/kg and 14.21 W/kg leading to an approximated maximum heating of 0.2–6.3 K per turbulence event. These are in the same range as the daily chemical heating rates, which apparently stresses the importance of dynamical energy conversion in the UMLT.

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Abstract. Between December 2013 and August 2017 the instrument FAIM (Fast Airglow IMager) observed the OH airglow emission at two Alpine stations. One year of measurements was performed at Oberpfaffenhofen, Germany (48.09° N, 11.28° E) and two years at Sonnblick, Austria (47.05° N, 12.96° E). Both stations are part of the Network for the detection of mesospheric change (NDMC). The temporal resolution is two frames per second and the field of view is 55 km × 60 km and 75 km × 90 km at the OH layer altitude of 87 km with a spatial resolution of 200 m and 280 m per pixel, respectively. This results in two dense datasets allowing precise derivation of horizontal gravity wave parameters. The analysis is based on a two-dimensional Fast Fourier Transform with fully automatic peak extraction. By combining the information of consecutive images time-dependent parameters such as the horizontal phase speed are extracted. The instrument is mainly sensitive to high-frequency small- and medium-scale gravity waves. A clear seasonal dependency concerning the meridional propagation direction is found for these waves in summer in direction to the summer pole. The zonal direction of propagation is eastwards in summer and westwards in winter. Investigations of the data set revealed an intra-diurnal variability, which may be related to tides. The observed horizontal phase speed and the number of wave events per observation hour are higher in summer than in winter.