The concatenation of Suzukicoupling and Buchwald-Hartwiga minationi naconsecutive multicomponent reactiono pens ac oncise, modular and efficient one-pot approach to diversely functionalized heterocycles, as exemplified for 3,10-diaryl 10H-phenothiazines, 3,9-diaryl9 Hcarbazoles, and 1,5-diaryl 1H-indoles, in high yields starting from simple staringm aterials. Moreover,t his one-pot reactioni sasequentially palladium-catalyzed process that does not require additional catalystl oading after the first coupling step.
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