We report here the processing and properties of transparent glass and glass-ceramic nanocomposites in the Li 2 O-Ta 2 O 5 -SiO 2 -Al 2 O 3 system in the presence of Eu 2 O 3 as luminescent probe. The formation of the LiTaO 3 crystal phase, the crystallite size, and the morphology with the progression of heat treatment have been examined by X-ray diffraction (XRD), transmission electron microscopy (TEM), and Fourier transformed infrared reflectance spectroscopy measurements. The crystallite sizes obtained from XRD and TEM are found to increase with heat-treatment time and vary in the range of 2-20 nm. The measured photoluminescence spectra exhibit emission transitions of 5 D 0,1 -7 F j (j 5 0, 1, 2, 3, and 4) of Eu 31 ions. From the nature of the emission transitions, the site symmetry in the vicinity of Eu 31 ions has been found to be near C 3v in the glass-ceramic nanocomposites. An inverse correlation has been observed between the asymmetric ratio (I ED /I MD ) of Eu 31 ions and the dielectric constant (e r ), with an increase in the heat-treatment time of glass, which is caused by the dipole-dipole interaction.
J. Ballato-contributing editorThis work was financially supported by BRNS/DAE under sanction no. 2007/34/05-BRNS.
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