In oxide nuclear fuels, at high burn-up or during high temperature periods such as ramp tests, out-ofpile heating tests, or any irradiations at high linear heat rates, fission gases can form micrometric or quasi-micrometric bubbles. During nominal operations, these bubbles participate to the pellet swelling, to the decrease of the fuel thermal conductivity and are involved in the mechanisms leading to fission gas release. During events involving a temperature increase, the resulting increase in the internal pressure of the bubbles might play a role in fuel fragmentation and in the opening of grain boundaries. The gas densities inside these bubbles are therefore one of the useful experimental information for the understanding of the fuel behaviour, and for the fuel behaviour code progress and validation. Two methods were developed to evaluate the gas density in the quasi-micrometric bubbles, using electron probe micro analyser, secondary ion mass spectrometry and focused ion beam scanning electron microscope together. The first method provides a mean gas density for all quasi-micrometric bubbles in a given area. The second method provides a gas density in a single selected bubble. In addition to the gas density, the 3D size and shape of the selected bubble is measured and can be related to the gas density result. In this work, these methods were applied to the bubbles formed in the centre of a PWR Cr doped UO 2 at 38.8 GWd/t U after a ramp test in the Osiris reactor, with a 12 h plateau at 470 W/cm, and to the bubbles formed in a PWR Cr doped UO 2 at 62.8 GWd/t U in the centre of the pellet and on the bubbles of the high burn-up structure on the rim. Both show the high pressures reached in these bubbles.
Focussed ion beam - scanning electron microscope (FIB-SEM) 3D examination was conducted on three standard UO2 and one Cr doped UO2 high burn-up pressurized water reactor (PWR) fuel samples. This work complemented other microanalysis examination, including an electron backscattered diffraction (EBSD) work on the polished surface. A parallel article giving the EBSD results was submitted simultaneously. Together, they found, in all the central area of these high burn-up samples: (i) a restructuring of the initial grains into smaller sub-grains forming low angle boundaries and with crystal orientations around that of their parent grains; and (ii) intragranular bubbles mostly situated on these low angle boundaries. The FIB-SEM 3D examination showed how such inter-sub-grain bubbles start as small compact but also small lenticular bubbles, similar to typical small intergranular lenticular bubbles. With increasing burn-up, these lenticular bubbles get thicker and locally interlink to form more complex bubbles. However, no long distance networks, between the sub-grains or between the original grains, were found. Such networks could have been a path for part of the fission gases to reach the grain boundaries, the grain edges (the intersection line of three grain boundaries), and the rod free volumes. These FIB-SEM 3D examinations brought details on the intragranular and intergranular bubbles situation for each studied volume. The distribution of the intragranular bubbles according to their sizes and shapes was exposed. The central restructuring, studied in this work, is likely to play a role in the increase of the fission gas release fractions at high burn-up. This work is an incentive to study further this restructuring and the bubbles formed, combining different approaches.
This paper discusses the use of electron backscattered diffraction to characterize restructuring in a set of UO2 samples, irradiated in a pressurized water reactor at a burn-up between 35 and 73 GWd/tU, including standard UO2 samples and Cr-doped UO2 samples, to provide a better understanding of restructuring occurring both on the periphery and in the center of high-burn-up pellets. The formation of a high burn-up structure on the periphery of high burn-up UO2 was confirmed in our experiment. We found restructuring associated with bubble formation of all the samples in the central area, with higher irradiation temperatures when the burn-up exceeded 61 GWd/tU, regardless of their initial microstructure. This restructuring tended to progress with the increasing burn-up and to sub-divide the initial grains into sub-grains, with orientations close to that of the parent grains. Radial changes and differences between these samples showed that the burn-up and the temperature were not the only relevant parameters involved in restructuring.
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