Long-chain polyphosphates can bridge clay particles leading to new arrested systems: all-inorganic aqueous Wigner glasses. These materials may have use in agriculture and health sciences.
Catalysts were synthesized with Ni and bentonite clay, without previous treatment, through wet impregnation with 5, 10 and 20% of Ni (m/m). They were characterized by energy dispersive X-ray fluorescence spectrometry (EDX), X-ray diffraction (XRD), temperature-programmed reduction (TPR), thermogravimetric analysis (TGA), adsorption and desorption of N2 at 77 K, and transmission electron microscopy (TEM). The catalytic activity in relation to the methane conversion reaction was evaluated at 500 °C for 0.5 h. The addition of 10 and 20% of nickel to the clay led to a disordered bentonite structure, characterized by the disappearance of the 001 reflection on the X-ray diffractograms, with a consequent increase in the interaction between nickel oxide and clay (TPR). All catalysts synthesized showed catalytic activity in relation to the conversion of methane to form ordered carbon. The catalyst with 20% of nickel had the highest activity, with 74% of methane conversion.
Disposal of plastics into the environment has been one of the major problems for the environment. The accumulation of polystyrene (PS) occurs in an accelerated way and, therefore, its reuse is challenging. Polystyrene nanocomposites impregnated with Ag nanoparticles (PS/AgNP) are generated from polystyrene residues and can be applied in the catalytic and plasmonic photo-catalytic reduction of phenolic compounds such as p-nitrophenol (PNP) to p-aminophenol (PAP). The AgNP were synthesized by a reverse micelle method resulting in nanoparticles with sizes in a range of 31.1-34.0 nm. The organocolloid was characterized by UV-Vis and dynamic light scattering (DLS), demonstrating the preparation of spherical nanoparticles. The preparation of the PS/AgNP, obtained using a thermally induced phase separation method (TIPS), was confirmed by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), laser-induced breakdown spectroscopy (LIBS), and Fourier transform visible infrared spectroscopy (FTIR). Nanocomposites showed impressive performance in the catalytic and plasmonic photocatalytic reduction under blue light irradiation, reaching up to 98% conversion, being a promising material for wastewater treatment as well as other various environmental issues. We used blue light to observe the plasmonic effect of silver nanoparticles, and no previous reports of this composite for PNP reduction using blue light photocatalysis were found.
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