An investigation of waste‐migration patterns from a septic system indicates that complex patterns result from minor variations in regolith adsorptive capacity and texture, local hydrology, and possibly soil microbiology. The existence of multichemical, bifurcating plumes suggest that monitor wells arranged up and downgradient and capable of multilevel sampling are essential to adequately delineate contaminant migration in ground water. The data also indicate that sampling for a single constituent could yield misleading information about the nature and distribution of other ground‐water contaminants. The ability for chemical removal by the regolith is in direct response to minor variations in silt‐ and clay‐sized particle content and corresponds to Langmuir adsorption isotherms. Silt‐ and clay‐sized particles are dominantly organic in origin. Minor iron and aluminum hydroxyoxides and clays are present. Substrate samples, when collected at regular intervals and analyzed for adsorbed constituents and textural variability, provide an integrated picture of the distribution of waste chemicals through time. Such samples also provide insight into the mechanics of plume configuration and flow characteristics within the regolith. The study shows that regolith adsorption data are essential to the determination of life expectancy of the regolith as a contaminant treatment system.
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