Understanding the mechanical properties of nanowires made of semiconducting materials is central to their application in nano devices. This work presents an experimental and computational approach to unambiguously quantify size effects on the Young's modulus, E, of ZnO nanowires and interpret the origin of the scaling. A micromechanical system (MEMS) based nanoscale material testing system is used in situ a transmission electron microscope to measure the Young's modulus of [0001] oriented ZnO nanowires as a function of wire diameter. It is found that E increases from approximately 140 to 160 GPa as the nanowire diameter decreases from 80 to 20 nm. For larger wires, a Young's modulus of approximately 140 GPa, consistent with the modulus of bulk ZnO, is observed. Molecular dynamics simulations are carried out to model ZnO nanowires of diameters up to 20 nm. The computational results demonstrate similar size dependence, complementing the experimental findings, and reveal that the observed size effect is an outcome of surface reconstruction together with long-range ionic interactions.
An experimental and computational approach is pursued to investigate the fracture mechanism of [0001] oriented zinc oxide nanowires under uniaxial tensile loading. A MEMS-based nanoscale material testing stage is used in situ a transmission electron microscope to perform tensile tests. Experiments revealed brittle fracture along (0001) cleavage plane at strains as high as 5%. The measured fracture strengths ranged from 3.33 to 9.53 GPa for 25 different nanowires with diameters varying from 20 to 512 nm. Molecular dynamic simulations, using the Buckingham potential, were used to examine failure mechanisms in nanowires with diameters up to 20 nm. Simulations revealed a stress-induced phase transformation from wurtzite phase to a body-centered tetragonal phase at approximately 6% strain, also reported earlier by Wang et al. (1) The transformation is partial in larger nanowires and the transformed nanowires fail in a brittle manner at strains as high as 17.5%. The differences between experiments and computations are discussed in the context of (i) surface defects observed in the ZnO nanowires, and (ii) instability in the loading mechanism at the initiation of transformation.
Nanowires made of materials with noncentrosymmetric crystal structure are under investigation for their piezoelectric properties and suitability as building blocks for next-generation self-powered nanodevices. In this work, we investigate the size dependence of piezoelectric coefficients in nanowires of two such materials - zinc oxide and gallium nitride. Nanowires, oriented along their polar axis, ranging from 0.6 to 2.4 nm in diameter were modeled quantum mechanically. A giant piezoelectric size effect is identified for both GaN and ZnO nanowires. However, GaN exhibits a larger and more extended size dependence than ZnO. The observed size effect is discussed in the context of charge redistribution near the free surfaces leading to changes in local polarization. The study reveals that local changes in polarization and reduction of unit cell volume with respect to bulk values lead to the observed size effect. These results have strong implication in the field of energy harvesting, as piezoelectric voltage output scales with the piezoelectric coefficient.
We characterized the elastic properties of GaN nanowires grown along different crystallographic orientations. In situ transmission electron microscopy tensile tests were conducted using a MEMS-based nanoscale testing system. Complementary atomistic simulations were performed using density functional theory and molecular dynamics. Our work establishes that elasticity size dependence is limited to nanowires with diameters smaller than 20 nm. For larger diameters, the elastic modulus converges to the bulk values of 300 GPa for c-axis and 267 GPa for a- and m-axis.
Characterization of atomic composition and spatially resolved dopant distribution in wide band gap semiconducting nanowires is critical for their applications in next-generation nanoelectronic and optoelectronic devices. We have applied laser-assisted atom probe tomography to measure the spatially resolved composition of wide band gap semiconducting undoped GaN nanowires and Mg-doped GaN nanowires. Stoichiometric evaporation of individual GaN nanowires was achieved, and optimal experimental conditions to characterize the concentration and spatial distribution of the dopant in the Mg:GaN nanowire samples were established. Extremely mild operating conditions, with laser pulse energy as low as 3 pJ, are required to avoid preferential loss of nitrogen and achieve stoichiometric evaporation. The role of nanowire morphology in the selection of optimal experimental conditions is discussed in the context of thermal transport within the nanowire under a heat load imposed by the pulsing laser. The results of this work are expected to help guide similar atom probe tomography studies of related wide band gap III–V semiconductor alloys, which will facilitate a better understanding of material response and will help develop structure–property relationships.
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