Banknotes are often found in high‐profile crimes such as armed robberies, bribery, and terrorist activity. However, such exhibits present a challenge to forensic operatives regarding fingermarks development, due to their mass quantities, potential for fingermarks on both sides, and their unique complex background in terms of color, irregular patterns, and topography. Hence, the standard development protocols become inefficient, due to the difficulty in achieving high contrast images over the background. This study focused on finding an operational sequence that would minimize the time of work on polymer banknotes, in terms of both development and image processing. Thirty‐two fingermarks were developed by vacuum metal deposition (VMD), black magnetic powder, and cyanoacrylate fuming (CA) followed by visualization and imaging by reflected short‐wave UV (RUVIS) (96 in total), showing a distinct advantage to the CA and RUVIS imaging over the other two techniques with a 75% success rate in the dark and high background regions, due to its physical principle which neutralizes high background interference. The images were then scanned by the automatic fingerprint identification system (AFIS) to test its ability to correctly differentiate false background features from real ones, again, showing a superiority of the RUVIS with 63% of the total initial marked features, being real. Overall, the CA and RUVIS sequence was found to be an ultimate method for multiple, same‐type surfaces, with the RUVIS capable of visualization and capturing of the images simultaneously, significantly reducing the time of development and image processing.
A self-assembled supramolecular dimeric entity via an exceptionally short (2.404 Å) and strong (22.9 kcal mol(-1)) [O-H-O](-) hydrogen bond is the key to the special reactivity of vasarenes with fluoride salts. Vasarene is a self-assembled, vase-shaped compound, obtained by the reaction between ninhydrin and phloroglucinol. Analogous compounds are prepared by replacing the phloroglucinol with other polyhydroxy aromatics. Vasarenes show special affinity towards compounds of the type M(+)F(-), where M being a large monovalent cation, producing ion-pair-vasarene adducts. The first step in the proposed mechanism is the dissociation of the M(+)F(-) salt releasing F(-) to the solution, which may provide an explanation as to why only MF salts, which include large monovalent cations, undergo this reaction. From a practical point of view, the ease of their preparation and their special affinity towards fluoride salts make vasarenes potential means for salt separation. The readily formed dimeric structure with the very short [O-H-O](-) negative charge-assisted H-bond (-CAHB) can also be further used as a model in theoretical studies of such systems and understanding their role in biological processes.
The investigation of serious crime scenes, such as murder by stabbing, requires a meticulous reconstruction of the events that have led to the crime and can be based, among others, on the analysis of blood stains that could help to connect the suspect to the victim and to the crime scene. In particular, blood-contaminated fingermarks (FMs) that are commonly found on surfaces such as plaster walls in crime scenes [1] may provide crucial evidence to the Crime Scene Investigation (CSI) units for the identification of those involved. Such marks are
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