Pressure sensing is an important function of electronic skin devices. The development of pressure sensors that can mimic and surpass the subtle pressure sensing properties of natural skin requires the rational design of materials and devices. Here we present an ultrasensitive resistive pressure sensor based on an elastic, microstructured conducting polymer thin film. The elastic microstructured film is prepared from a polypyrrole hydrogel using a multiphase reaction that produced a hollow-sphere microstructure that endows polypyrrole with structure-derived elasticity and a low effective elastic modulus. The contact area between the microstructured thin film and the electrodes increases with the application of pressure, enabling the device to detect low pressures with ultra-high sensitivity. Our pressure sensor based on an elastic microstructured thin film enables the detection of pressures of less than 1 Pa and exhibits a short response time, good reproducibility, excellent cycling stability and temperature-stable sensing.
Pressure sensitivity and mechanical self-healing are two vital functions of the human skin. A flexible and electrically conducting material that can sense mechanical forces and yet be able to self-heal repeatably can be of use in emerging fields such as soft robotics and biomimetic prostheses, but combining all these properties together remains a challenging task. Here, we describe a composite material composed of a supramolecular organic polymer with embedded nickel nanostructured microparticles, which shows mechanical and electrical self-healing properties at ambient conditions. We also show that our material is pressure- and flexion-sensitive, and therefore suitable for electronic skin applications. The electrical conductivity can be tuned by varying the amount of nickel particles and can reach values as high as 40 S cm(-1). On rupture, the initial conductivity is repeatably restored with ∼90% efficiency after 15 s healing time, and the mechanical properties are completely restored after ∼10 min. The composite resistance varies inversely with applied flexion and tactile forces. These results demonstrate that natural skin's repeatable self-healing capability can be mimicked in conductive and piezoresistive materials, thus potentially expanding the scope of applications of current electronic skin systems.
A crystal's structure has significant impact on its resulting biological, physical, optical and electronic properties. In organic electronics, 6,13(bis-triisopropylsilylethynyl)pentacene (TIPS-pentacene), a small-molecule organic semiconductor, adopts metastable polymorphs possessing significantly faster charge transport than the equilibrium crystal when deposited using the solution-shearing method. Here, we use a combination of high-speed polarized optical microscopy, in situ microbeam grazing incidence wide-angle X-ray-scattering and molecular simulations to understand the mechanism behind formation of metastable TIPS-pentacene polymorphs. We observe that thin-film crystallization occurs first at the air-solution interface, and nanoscale vertical spatial confinement of the solution results in formation of metastable polymorphs, a one-dimensional and large-area analogy to crystallization of polymorphs in nanoporous matrices. We demonstrate that metastable polymorphism can be tuned with unprecedented control and produced over large areas by either varying physical confinement conditions or by tuning energetic conditions during crystallization through use of solvent molecules of various sizes.
A self-healing thermo-reversible elastomer is synthesized by cross-linking a hydrogen bonding polymer network with chemically-modified graphene oxide. This nanocomposite allows for both rapid and efficient self-healing (in only several minutes) at room temperature, without the need for any external stimuli (e.g., heating or light exposure), healing agents, plasticizers or solvents.
Developing
organic photovoltaic systems that possess high efficiency,
high reproducibility, and low cost remains a topic of keen investigation.
From a molecular design perspective, developing a “multicomponent”
copolymerization synthetic approach could potentially afford macromolecular
materials encompassing all of the aforementioned desired parameters.
Herein, we describe the synthesis of a series of poly(isoindigo-dithiophene)-based
conjugated polymers with varying amounts of low molecular weight polystyrene
(PS) side chains (M
n = 1300 g/mol) via
random copolymerization. We observed better solubility with polymers
containing the PS side chains (when compared to their non-PS-side-chain
counterparts), hence leading to better batch-to-batch reproducibility
in terms of molecular weights. Furthermore, the PS-side-chain-decorated
copolymers also demonstrated better thin film processability, without
affecting the electronic and optical properties, when the molar percentage
of the PS-containing repeating units were ≤10%. Bulk heterojunction
solar cell devices fabricated with these PS-containing copolymers
demonstrated significantly improved performances [maximum power conversion
efficiencies (PCE) > 7% and open circuit voltages (V
OC) ≥ 0.95 V], compared to the highest reported
performance (PCE = 6.3% and V
OC = 0.70)
based on similar isoindigo-containing polymers. Taken together, the
synthesis, processing, and device performances of PS-containing copolymers
represent a new approach in molecular engineering to achieve a balance
between the optical/electronic properties and solubility/processability
of reproducible polymeric systems.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.